Scientific American Supplement, No. 717, September 28, 1889Various
Science
Scientific American Supplement, No. 717, September 28, 1889
Various
Science -- Periodicals
As regards the chemistry of rock gas, we may remark in the first place
that this natural product ranks usually as light carbureted hydrogen
gas. In this respect it is not unlike the marsh gas with which
everyone is familiar, which is found bubbling up from swamps and
morasses, and which constitutes the "will o' the wisp" of romance. In
rock gas, marsh gas itself is actually found in the proportion of
about 93 per cent. The composition of marsh gas is very simple. It
consists of the two elements carbon and hydrogen united in certain
proportions, indicated chemically by the symbol CH4. We find, in fact,
that rock gas possesses a close relationship, chemically speaking,
with many familiar carbon compounds, and of these latter, petroleum
itself, asphaltum, coal, jet, graphite or plumbago, and even the
diamond itself--which is only crystallized carbon after all--are
excellent examples.
The differences between these substances really consist in the degree
of fixing of the carbon or solid portion of the product, as it were,
which exists. Thus in coal and jet the carbon is of stable character,
such as we might expect to result from the slow decomposition of
vegetable matter, and the products of this action are not volatile or
liable to be suddenly dissociated or broken up. On the other hand,
when we deal with the _hydrocarbons_ as they are called, in the shape
of rock gas, naphtha, petroleum, tar, asphaltum, and similar
substances, we see how the carbon has become subordinated to the
hydrogen part of the compounds, with the result of rendering them more
or less unstable in their character. As Professor M'Gee has shown us,
there is in truth a graduated series leading us from the marsh gas and
rock gas as the lightest members of this class of compounds onward
through the semi-gaseous naphtha to the fluid petroleum, the
semi-fluid tar, the solid asphaltum, and the rigid and brittle
substance known as albertite, with other and allied products. Having
said so much regarding the chemistry of the fuels of the future, we
may now pass to consider their geological record. A somewhat curious
distribution awaits the man of science in this latter respect. Most
readers are aware that the geologists are accustomed to classify
rocks, according to their relative age, into three great groups, known
respectively as the primary, secondary, and tertiary periods. In the
secondary period we do not appear to meet with the fuels of the
future, but as far back as the Devonian or old Red Sandstone period,
and in the still older Silurian rocks, stores of gas and petroleum
abound. In the latest or tertiary period, again, we come upon nearly
all the forms of fuels we have already specified.
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