Scientific American Supplement, No. 794, March 21, 1891Various
Science
Scientific American Supplement, No. 794, March 21, 1891
Various
Science -- Periodicals
The view generally adopted with regard to the theory of these
processes is that plaster consists of anhydrous calcium sulphate,
CaSO4, in a condition probably amorphous, different from that of
natural crystallized CaSO4, known to mineralogists under the name
of anhydrite. By the influence of a high temperature it appears
probable that a molecular change is gradually induced with production
of a crystalline structure, and probably an increase of specific
gravity, resulting in the artificial reproduction of the mineral
anhydrite. No determination appears to have been published of the
specific gravity of plaster prepared by complete baking at a low
temperature. The theory is, however, confirmed by the results obtained
by workers on the subject of mineralogical synthesis, who have shown
that the material which has been produced at high temperatures has the
specific gravity and other physical properties of the mineral
anhydrite.
It was formerly supposed that plaster prepared by baking at a
temperature above 300 degrees loses completely its power of setting.
Later observations, however, as those of Landrin, negative this view.
Between 300 degrees and 400 degrees Landrin obtained plasters setting
almost instantaneously when mixed with a small amount of water. When
the temperature employed approached 400 degrees, the set plaster was
softer, but the setting still took place quickly. These observations
appear to show that the change to anhydrite is a very gradual process
at temperatures below a red heat.
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