Scientific American Supplement, No. 794, March 21, 1891Various
Science
Scientific American Supplement, No. 794, March 21, 1891
Various
Science -- Periodicals
The explanation of the setting of plaster was first given by
Lavoisier, who pointed out that gypsum is an hydrated salt, and that
the set plaster is in fact gypsum reformed, the change brought about
by baking being merely loss of water of crystallization. The beds of
gypsum of most importance both formerly and at the present time in the
plaster manufacture occur in the neighborhood of Paris in the lower
tertiary formation. Different beds differ (1) in respect of character
and quantity of admixed materials and (2) in the structure of the
gypsum itself. With regard to the first point, some deposits contain a
notable proportion of carbonate of lime, a fact which under certain
circumstances may considerably influence the character of the plaster.
In the matter of structure two principal varieties occur (1) granular
and (2) fibrous. Further, hardness of the granular kind varies
considerably. These differences of structure in the original material
appear to exercise an influence on the properties of the plaster. Thus
according to Payen the plaster formed from the granular variety sets
more gradually than that derived from the fibrous, and forms a denser
mass. The softer kinds of the granular gypsum are those principally
used in the production of plaster for the moulds of potteries.
In the old fashioned process which is still employed for making the
common kinds of plaster, the material is exposed to the direct action
of flame. Large lumps are placed in the lower part of the furnace,
above them smaller lumps, and, after the heating has been carried on
for some time, finely divided material is filled in at the top. The
outer portion of the larger lumps is always overburnt, and in the
upper part of the furnace the presence of shining crystalline
particles generally indicates the fact that some gypsum has remained
unchanged. Provided that the amount of unburnt and overburnt material
does not exceed about 30 per cent. of the total, the plaster is
suitable for many applications.
It was early observed that set plaster could be revivified by a second
baking, but attempts in this direction were not uniformly successful,
it being found that the dehydrated substance in some cases refused to
set with water. It behaved in fact similarly to the natural anhydrous
calcium sulphate which is unaffected by water. These failures were
found to be due to the employment of too high a temperature, and such
plaster was termed _dead burnt_. Although this fact was ascertained
long ago, yet ignorance of what had already been done has probably
been the cause of many disappointments in attempts at revivification
which have been made from time to time by persons unacquainted with
the history of the subject.
Public-domain text, read in full here on John Shaqi.
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