Scientific American Supplement No. 822, October 3, 1891Various
Science
Scientific American Supplement No. 822, October 3, 1891
Various
Science -- Periodicals
On the other hand, if due observance is not paid to these conditions,
the sources of error are numerous, and inaccurate results inevitable.
We will endeavor to point out in this report the best means of meeting
the proper conditions for obtaining the highest degree of accuracy
consistent with fairly rapid work. It would be manifestly impossible
to observe so great a refinement of accuracy in this work as would be
employed in exact scientific research.
This would be unnecessary for the end in view, and impossible on
account of the amount of time that would be required.
I.--INSTRUMENTS AND APPARATUS.
It is of the greatest importance that the polariscopes and all
apparatus used in the work shall be carefully and accurately adjusted
and graduated, and upon a single and uniform system of standardization.
Recent investigations of the polarimetric work done in the customs
branch of the Treasury Department have shown that a very considerable
part of the want of agreement in the results obtained at the different
ports was due to a lack of uniformity in the standardization of the
instruments and apparatus.
_(a.) The Polariscope._--There are many different forms of this
instrument used. Some are adapted for use with ordinary white light,
and some with monochromatic light, such as sodium ray. They are
graduated and adjusted upon various standards, all more or less
arbitrary. Some, for example, have their scales based upon the
displacement of the polarized ray produced by a quartz plate of a
certain thickness; others upon the displacement produced by an
arbitrary quantity of pure sucrose, dissolved and made up to a certain
volume and polarized in a certain definite length of column. It would
be very desirable to have an absolute standard set for polariscopic
measurements, to which all instruments could be referred, and in the
terms of which all such work could be stated. This commission has
information that an investigation is now in progress under the
direction of the German imperial government, having for its end and
purpose the determination of such data as will serve for the
establishment of an absolute standard. When this is accomplished it
can easily be made a matter of international agreement, and all future
forms of instruments be based upon it. This commission would suggest
that the attention of the proper authorities should be called to the
desirability of official action by this government with a view to
co-operation with other countries for the adoption of international
standards for polarimetric work. Until this is done, however, it will
be necessary for the Internal Revenue Bureau to adopt, provisionally,
one of the best existing forms of polariscope, and by carefully
defining the scale of this instrument, establish a basis for its
polarimetric work which will be a close approximation to an absolute
standard, and upon which it can rely in case of any dispute arising as
to the results obtained by the officers of the bureau.
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