Scientific American, Vol. XXXVII.—No. 2. [New Series.], July 14, 1877: A Weekly Journal of Practical Information, Art, Science, Mechanics, Chemistry, and ManufacturesVarious
Science
Scientific American, Vol. XXXVII.—No. 2. [New Series.], July 14, 1877: A Weekly Journal of Practical Information, Art, Science, Mechanics, Chemistry, and Manufactures
Various
Science -- Periodicals; Technology -- Periodicals
Over 3,000 teachers' positions are said to be vacant at the present
time.
* * * * *
BLEACHING SILK AND WOOL.
The methods now in use for bleaching silk, wool, and all animal
fibers, such as sulphurous acid, alkalies, soap, etc., are so
imperfect that Tessié du Motay has patented the following process,
involving the use of binoxide of barium, with or without the addition
of permanganates. The binoxide of barium is pulverized and subjected
to the action of carbonic acid to remove any unconverted caustic
baryta present. It is then thrown into boiling water, and after the
bath has partially cooled the materials to be bleached are introduced
and the bath kept at a temperature of 86° Fah. to 194° Fah. for two
hours; silk from wild silkworms requiring a higher temperature than
wool, goat's hair, and the like. It is then taken out and washed, put
into an acid bath, then washed again. If necessary, the barium bath
is repeated, as also the subsequent washings. If this second bath of
binoxide of barium does not produce the requisite whiteness, it is
introduced into a solution of permanganic acid or permanganate of
magnesia before the last washing.
Binoxide of Barium, BaO_{2}, is made by subjecting the oxide or
caustic baryta, BaO, to a stream of oxygen or common air at a high
temperature. Its bleaching action is probably due to the formation of
peroxide of hydrogen in solution in the bath.
* * * * *
AN ALLOY OF TIN AND PHOSPHORUS.
At the Graupen Tin Works, in Bohemia, an alloy of tin and phosphorus
is made containing the greatest possible quantity of phosphorus which
the tin is able to retain without losing any of it upon repeated
meltings. This compound, which is neither entitled to the name of
alloy nor is it a phosphide of tin, is employed in the manufacture
of phosphorus-bronze. In the manufacture of phosphorus-bronze, by
alloying copper with phosphorus-tin, no other precautions require to
be observed than in the preparation of common bronze. As the different
properties of phosphorus-bronze depend upon the proportions of
phosphorus and of tin, two kinds of phosphorus-tin are prepared. No.
0 contains 5 per cent., and No. 1, 2½ per cent. of phosphorus. These two
kinds suffice to make the greater part of all the desired mixtures.
For special purposes, the Graupen Works make to order phosphorus-tin
with any desired quantity of phosphorus not exceeding 5 per
cent., which is the highest possible limit. It is claimed
that phosphorus-bronze may be manufactured by the use of this
phosphorus-tin as much as 40 per cent. cheaper than that now in the
market, while it will only cost 8 per cent. more than the ordinary tin
and copper bronze.
No details are given of the method employed to make the phosphorus
combine with tin, but the low melting point of tin as compared with
that of copper would indicate that this would lead to the great saving
promised above.
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