Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
First, then, in regard to the mass or weight of the molecules. So far as
their relative values are concerned, chemistry gives us the means of
determining the molecular weights with very great accuracy; but when we
attempt to estimate their weights in fractions of a grain--the smallest
of our common standards--we can not expect precision, simply because the
magnitudes compared are of such a different order; and the same is true
of most of the other absolute dimensions, such as the diameter and
volume of the molecules. We only regard the values given in our table as
a very rough estimate, but still we have good grounds for believing that
they are sufficiently accurate to give us a true idea of the order of
the quantities with which we are dealing; and it will be seen that,
although the numbers required to express the relations to our ordinary
standards are so large, these molecular magnitudes are no more removed
from us on the one side than are those of astronomy on the other.
Passing next to the velocity of the molecular motion, we find in that a
quantity which, although large, is commensurate with the velocity of
sound, the velocity of a rifle-ball, and the velocities of many other
motions with which we are familiar. We are, therefore, not comparing, as
before, quantities of an utterly different order, and we have confidence
that we have been able to determine the value within very narrow limits
of error. But how surprising the result is! Those molecules of hydrogen
are constantly moving to and fro with this great velocity, and not only
are the molecules of all aeriform substances moving at similar, although
differing rates, but the same is equally true of the molecules of every
substance, whatever may be its state of aggregation.
The gas is the simplest molecular condition of matter, because in this
state the molecules are so far separated from each other that their
motions are not influenced by mutual attractions. Hence, in accordance
with the well-known laws of motion, gas molecules must always move in
straight lines and with a constant velocity until they collide with each
other or strike against the walls of the containing vessel, when, in
consequence of their elasticity, they at once rebound and start on a new
path with a new velocity. In these collisions, however, there is no loss
of motion, for, as the molecules have the same weight and are perfectly
elastic, they simply change velocities, and whatever one may lose the
other must gain.
But, if the velocity changes in this way, you may ask, What meaning has
the definite value given in our table? The answer is, that this is the
mean value of the velocity of all the molecules in a mass of hydrogen
gas under the assumed conditions; and, by the principle just stated, the
mean value can not be changed by the collisions of the molecules among
themselves, however great may be the change in the motion of the
individuals.
Public-domain text, read in full here on John Shaqi.
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