Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
The transparency of soap is generally due to the presence of alcohol,
sugar or glycerine in the soap when it is made. It is very essential in
a soap of this character, where lightness and clearness of color are
desired, that the material for making the soap be carefully selected as
to color and purity. The perfumes also play an important part in the
color of the soap and many of the tinctures, balsams and infusions used
in perfuming soap may eventually cause trouble by spotting. If the soap
is artificially colored, which is almost always the case, the dyestuffs
used for this purpose should have careful attention and only those
should be used which are known to resist the action of alkalis. Where
rosin is used this product must be of the better grade. Distilled water
is always preferable for use in transparent soap. The government permits
the use of a specially denatured alcohol. This alcohol is not taxed and
consists of grain (ethyl) alcohol denatured with 5 per cent. wood
(methyl) alcohol. Some soapmakers prefer to use a more expensive refined
methyl alcohol, but outside of adding to the cost of the soap, there is
no particular advantage. The glycerine should be chemically pure. As to
the oils and fats these should be low in acid and of good color. Under
no circumstances should the crutcher or kettle in which the soap is made
be rusty or unclean in any way. For a light soap enameled utensils are
to be preferred.
To obtain transparency in soap the following general methods may be
given.
1. Where the transparency is due to sugar.
2. Where alcohol and glycerine produce transparency.
3. Where (1) or (2) is supplemented by the use of castor oil.
4. Where transparency depends upon the percentage of fatty acid in a
soap and the number of times the soap is milled.
Under the first method at least 25 per cent. of the charge should be
cocoanut oil, the other constituent being tallow or any fat or oil
capable of giving a sufficiently hard soap. The soap is boiled and
finished as usual, then run to the crutcher to be mixed with a strong
cane sugar solution, containing 10-20 per cent. sugar of the weight of
the soap. The sugar is dissolved in its own weight of water and the
solution heated to 175 degs. F. before being very slowly added to the
soap. As the water evaporates, soaps of this type show spots due to the
sugar thus being thrown out of solution.
Transparent soap made under the second method may be saponified as usual
and consist of any good toilet base. The soap is run to the crutcher and
mixed with 95 per cent. alcohol in the proportion of one part alcohol to
two parts of fatty acid contained in the soap together with glycerine in
the same proportion.
By the third method castor oil alone may be used to make the soap or
added to any of the above bases up to 33-1/3 per cent. of the charge. If
castor oil only is used, but 2 per cent. or 3 per cent. of sugar is
required.
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