Quartz and its allied rocks—jasper, hornstone, siliceous schist, etc., are all, as already stated, acted on with difficulty by the “weathering” agencies. Crystalline quartz rock may be considered as practically refractory against all but the mechanical agencies, and hence remains in the form of sand and gravel, more or less rounded by attrition, as a prominent component of most soils; sometimes to the extent of over 92 per cent, even in soils highly esteemed in cultivation, especially in the arid region. Such soils are mostly the result of the disintegration of sandstones, the cement of which has been dissolved out in the course of weathering; or they may be derived directly from geological deposits of more or less loose and unconsolidated sand. Among crystalline rocks, granites, gneiss and mica-schists are those most usually concerned in the formation of sandy soils; since in common parlance, quartz is understood to be the substance of the sand unless otherwise stated. The exceptions are especially important in the regions of deficient rainfall. But while crystalline quartz is practically insoluble in all natural solvents, the same is not true of the jaspers and hornstones. These consist of a mixture of crystalline and amorphous (non-crystalline) silica, which is more readily soluble than the crystalline, and is attacked by many natural waters, especially by those containing even very small amounts of the carbonates of potash or soda. We thus often find that hornstone and jasper pebbles buried in the soil, while still hard internally, have externally been converted into a friable, almost chalky substance, consisting of crystalline quartz from which the cementing amorphous silex has been removed by the soil water. In the course of time such pebbles may be completely destroyed by this process, so as to be light and chalky throughout, and readily crushed in tillage. The change is the more striking when, as frequently happens, the hornstone pebble is traversed by small veins of crystalline quartz, which remain as a skeleton. _Solubility of Silica in Water._—It is easily shown experimentally that the compound of silica with water (hydrate) is under certain conditions readily soluble not only in pure water, but also in such as contains carbonic acid. It thus occurs in nearly all spring and well waters; some hot springs deposit large masses of it (sinter); and geological evidence clearly demonstrates that quartz veins have as rule been formed from water-solutions of silica. That silica in its soluble form circulates freely in the soil water, is abundantly evident from the large amounts of it which are secreted on the outside of the stems of grasses, horsetail rushes and other plants, imparting a gritty roughness to their outer surface. In the case of the giant bamboo grass of Asia, the silica accumulated on the outside of the joints forms a hard sheath of considerable thickness, known to commerce as tabashir.