Steam, Its Generation and UseBabcock & Wilcox Company
History
Steam, Its Generation and Use
Babcock & Wilcox Company
Steam-boilers, Water-tube
Table 15 gives the solubility of these mineral salts in water at various
temperatures in grains per U. S. gallon (58,381 grains). It will be seen
from this table that the carbonates of lime and magnesium are not
soluble above 212 degrees, and calcium sulphate while somewhat insoluble
above 212 degrees becomes more greatly so as the temperature increases.
Scale is also formed by the settling of mud and sediment carried in
suspension in water. This may bake or be cemented to a hard scale when
mixed with other scale-forming ingredients.
Corrosion--Corrosion, or a chemical action leading to the actual
destruction of the boiler metal, is due to the solvent or oxidizing
properties of the feed water. It results from the presence of acid,
either free or developed[15] in the feed, the admixture of air with the
feed water, or as a result of a galvanic action. In boilers it takes
several forms:
1st. Pitting, which consists of isolated spots of active corrosion which
does not attack the boiler as a whole.
2nd. General corrosion, produced by naturally acid waters and where the
amount is so even and continuous that no accurate estimate of the metal
eaten away may be made.
3rd. Grooving, which, while largely a mechanical action which may occur
in neutral waters, is intensified by acidity.
Foaming--This phenomenon, which ordinarily occurs with waters
contaminated with sewage or organic growths, is due to the fact that the
suspended particles collect on the surface of the water in the boiler
and render difficult the liberation of steam bubbles arising to that
surface. It sometimes occurs with water containing carbonates in
solution in which a light flocculent precipitate will be formed on the
surface of the water. Again, it is the result of an excess of sodium
carbonate used in treatment for some other difficulty where animal or
vegetable oil finds its way into the boiler.
Priming--Priming, or the passing off of steam from a boiler in belches,
is caused by the concentration of sodium carbonate, sodium sulphate or
sodium chloride in solution. Sodium sulphate is found in many southern
waters and also where calcium or magnesium sulphate is precipitated with
soda ash.
Treatment of Feed Water--For scale formation. The treatment of feed
water, carrying scale-forming ingredients, is along two main lines: 1st,
by chemical means by which such impurities as are carried by the water
are caused to precipitate; and 2nd, by the means of heat, which results
in the reduction of the power of water to hold certain salts in
solution. The latter method alone is sufficient in the case of certain
temporarily hard waters, but the heat treatment, in general, is used in
connection with a chemical treatment to assist the latter.
Before going further into detail as to the treatment of water, it may be
well to define certain terms used.
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