Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
(1) Drying alkyd resins.
(a) Unmodified.
(b) Modified with natural materials.
(c) Modified with other synthetic resins.
(d) Modified with other synthetic resins and oil extended.
(2) Semidrying alkyd resins.
(3) Nondrying alkyd resins.
(4) Miscellaneous modified alkyd resins.
(5) Alkyd resins in water dispersion.
(6) Alkyd resins in molding compositions.
At least 75 percent of the alkyd resin finishes used at present are of
the drying type and about 15 percent of the nondrying type.
_Unmodified drying alkyd resins._—This class of alkyd resins consists of
a series of compounds made from polyhydric alcohols, polybasic acids, and
fatty acids in chemical combination. The alcohol is usually glycerin, and
the polybasic acid largely phthalic anhydride or acid, although others,
such as maleic anhydride (acid) are increasing rapidly in importance. The
fatty acid or oil used may be linseed, tung, perilla, hempseed, soybean,
sunflower, safflower, or other drying oil. It is believed that tung oil
and perilla oil are the most important at this time.
Unmodified drying alkyd resins are characterized by excellent durability
but limited resistance to water in air-dried finishes. Both in air-dried
and in baked finishes they are outstanding as to flexibility, quick
drying, long luster life, and permanent adhesion. Their principal uses
are in finishes for interior walls and woodwork, automobiles, coatings on
steel such as for refrigerators, railway equipment, bridges, advertising
signs, and lithographed containers. In these applications the products
of this type compete with nitrocellulose lacquers and the older types
of varnishes and paints. While the initial cost is higher, greater
durability is obtained together with faster drying, flexibility, and
hardness.
Probably the largest field for surface coatings is outdoor wood finishes.
Several attempts have been made to adapt pure alkyd finishes to this
use but with limited success because the hard and non-porous finish
does not permit the escape of moisture contained in the wood and the
pressure developed from vaporization of the moisture by the sun’s rays
tends to lift the coating from the wood surface. Recently it has been
found practicable to incorporate from 15 to 20 percent alkyd resins in
conventional types of outdoor paints for wood. Here the use of alkyds has
contributed greater durability and retention of fresh appearance over a
longer period. Paints of this type are now on the retail market.
_Drying alkyd resins modified with natural materials._—This type of
alkyd resin is modified principally with natural resins, such as rosin,
damar, mastic, shellac, or copal. The use of these natural resins imparts
hardness to the resin but shortens its durability. They make the product
less expensive, permit easier incorporation of the drying oil, and in
some instances increase the water resistance.
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