Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
6. _Filtration_.--The infusion shall be filtered till optically clear
(_vide_ 2). No correction for absorption is needed for the Berkefeld
candle, or for S. and S. 590 paper [Footnote: Schleicher and Schüll,
Düren (Rheinland), Germany.] if a sufficient quantity (250-300 c.c.) is
rejected before measuring the quantity for evaporation, and the solution
may be passed through repeatedly to obtain a clear filtrate.
If other methods of filtration are employed, the average correction
necessary must be determined in the following manner:--About 500 c.c. of
the same or a similar tanning solution is filtered perfectly clear, and
after thorough mixing 50 c.c. is evaporated to determine "Total Soluble
A." A further portion is now filtered in the exact method for which the
correction is required (time of contact and volume rejected being kept
as constant as possible), and 50 c.c. is evaporated to determine "Total
Soluble B." The difference between "A" and "B" is the correction sought,
which must be added to the weight of the total solubles found in
analysis. An alternative method of determining correction, which is
equally accurate and often more convenient, is to filter a portion of
the tanning solution through the Berkefeld candle till optically clear,
which can be generally accomplished by rejecting 300 or 400 c.c., and
returning the remaining filtrate repeatedly; and at the same time to
evaporate 50 c.c. of the clear filtrate obtained by the method for which
correction is required, when the difference between the residues will be
the correction sought. An average correction must be obtained from at
least five determinations. It will be found that this is approximately
constant for all materials, and amounts in the case of S. and S. 605,
150 c.c. being rejected, to about 0.005 gm., and where 2 gm. of kaolin
are employed in addition to 0.0075 gm. The kaolin must be previously
washed with 75 c.c. of the same liquor, which is allowed to stand
fifteen minutes and then poured off. Paper 605 has a special absorption
for a yellow colouring matter often contained in sulphited extracts.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account