The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' AssociationSmith, Watson
Science
The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' Association
Smith, Watson
Hats
_Borax._--A good deal of the Tuscan boric acid is used in France for the
manufacture of borax, which is a sodium salt of boric acid. Borax is
also manufactured from boronitrocalcite, a calcium salt of boric acid,
which is found in Chili and other parts of South America. The crude
boronitrocalcite or "tiza" is boiled with sodium carbonate solution,
and, after settling, the borax is obtained by crystallisation. Borax
itself is found in California and Nevada, U.S.A., and also in Peru,
Ceylon, China, Persia, and Thibet. The commercial product is obtained
from the native borax (known as "tincal") by dissolving in water and
allowing the solution to crystallise. The Peruvian borax sometimes
contains nitre. For testing the purity of refined borax the following
simple tests will usually suffice. A solution of the borax is made
containing 1 part of borax to 50 parts of water, and small portions of
the solution are tested as follows: _Heavy metals_ (_lead_, _copper_,
etc.).--On passing sulphuretted hydrogen into the solution, no
coloration or precipitate should be produced. _Calcium Salts._--The
solution should not give a precipitate with ammonium oxalate solution.
_Carbonates._--The solution should not effervesce on addition of nitric
or hydrochloric acid. _Chlorides._--No appreciable precipitate should
be produced on addition of silver nitrate solution and nitric acid.
_Sulphates._--No appreciable precipitate should be produced on adding
hydrochloric acid and barium chloride. _Iron._--50 c.c. of the solution
should not immediately be coloured blue by 0.5 c.c. of potassium
ferrocyanide solution.
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