The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' AssociationSmith, Watson
Science
The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' Association
Smith, Watson
Hats
The name or word "mordant" indicates the empiricism, or our old friend
"the rule of thumb," of the age in which it was first created and used.
It serves as a landmark of that age, which, by the way, needed
landmarks, for it was an age of something between scientific twilight
and absolute darkness. _Morder_ in French, derived from the Latin
_mordere_, means "to bite," and formerly the users of mordants in dyeing
and printing believed their action to be merely a mechanical action,
that is, that they exerted a biting or corroding influence, serving to
open the pores of the fabrics, and thus to give more ready ingress to
the colour or dye.
Most mordants are salts, or bodies resembling salts, and hence we must
commence our study of mordants by a consideration of the nature of
salts. I have already told you that acids are characterised by what we
term an acid reaction upon certain vegetable and artificial colours,
whilst bases or basic substances in solution, especially alkalis,
restore those colours, or turn them to quite another shade; the acids do
the one thing, and the alkalis and soluble bases do the opposite. The
strongest and most soluble bases are the alkalis--soda, potash, and
ammonia. You all know, probably, that a drop of vitriol allowed to fall
on a black felt hat will stain that hat red if the hat has been dyed
with logwood black; and if you want to restore the black, you can do
this by touching the stain with a drop of strong ammonia. But the use
of a black felt hat as a means of detecting acidity or alkalinity would
not commend itself to an economic mind, and we find a very excellent
reagent for the purpose in extract of litmus or litmus tincture, as well
as in blotting paper stained therewith. The litmus is turned bright red
by acids and blue by alkalis. If the acid is exactly neutralised by,
that is combined with, the alkaline base to form fully neutralised
salts, the litmus paper takes a purple tint. Coloured reagents such as
litmus are termed indicators. A substance called phenolphthalein, a
coal-tar product, is a very delicate indicator; it is more sensitive to
acids than litmus is. Now there are some salts which contain a
preponderance of acid in their composition, _i.e._ in which the acid has
not been fully neutralised by the base; such salts are termed acid
salts. Bicarbonate of soda is one of these acid salts, but so feeble is
carbonic acid in its acid properties and practical evidences, that we
shall see both monocarbonate or "neutral" carbonate of soda and
bicarbonate or "acid" carbonate of soda show evidences of, or, as
chemists say, react with alkalinity towards litmus. However,
phenolphthalein, though reacting alkaline with monocarbonate of soda,
indicates the acidity of the bicarbonate of soda, a thing which, as I
have just said, litmus will not do. We will take two jars containing
solution of monocarbonate of soda, and in the first we will put some
phenolphthalein solution, and in the second, some litmus tincture. The
Public-domain text, read in full here on John Shaqi.
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