The Chemistry of Plant LifeThatcher, Roscoe Wilfred
Science
The Chemistry of Plant Life
Thatcher, Roscoe Wilfred
Botanical chemistry
The term "monosaccharides," as commonly used, refers to hexoses. It applies
equally well, however, to any other sugar-like substance which either
occurs naturally or results from the decomposition of more complex
carbohydrates, and which cannot be further broken down without destroying
its characteristic aldehyde-alcohol groups and sugar-like properties.
All such monosaccharides, being alcohol-aldehydes, can easily be reduced to
the corresponding polyatomic alcohols, containing the same number of carbon
atoms as the original monosaccharides, each with one OH group attached to
it. All aldose monosaccharides are converted, by gentle oxidation, into the
corresponding monobasic acid, having a COOH group in the place of the
original CHO group. Further oxidation either changes the alcoholic groups
into COOH groups, producing polybasic acids, or breaks up the chain. When
ketose monosaccharides are submitted to similar oxidation processes, they
are broken down into shorter chain compounds.
The various monosaccharides which have thus far been found as constituents
of plant tissues, or as parts of other more complex compounds which occur
in plants, are shown in the following table:
_Trioses_ (C_{3}H_{6}O_{3}) _Tetroses_ (C_{4}H_{8}O_{4})
Aldose--Glyceric aldehyde, Aldoses--_d_- and _l_-Erythrose,
or glycerose _l_-Threose
Ketose--Dioxyacetone
_Pentoses_ (C_{5}H_{10}O_{5}) _Methyl Pentoses_ (C_{6}H_{12}O_{5})
Aldoses--_d_- and _l_-Arabinose Aldoses--Rhamnose
_d_- and _l_-Xylose Fucose
_l_-Ribose Rhodeose
_l_-Lyxose Chinovose
_Hexoses_ (C_{6}H_{12}O_{6})
Mannitol series Dulcitol series
Aldoses--_d_- and _l_-Glucose _d_- and _l_-Galactose
_d_- and _l_-Mannose _d_- and _l_-Talose
_d_- and _l_-Gulose
_d_- and _l_-Idose
_d_-Altrose
_d_-Allose
Ketoses-- _d_-Fructose _d_-Tagatose
_d_-Sorbose
_Heptoses_ _Octoses_ _Nonoses_
(C_{7}H_{14}O_{7}) (C_{8}H_{16}O_{8}) (C_{9}H_{18}O_{9})
Glucoheptose Gluco-octose Glucononose
Mannoheptose Manno-octose Mannononose
Galactoheptose Galacto-octose
Persuelose
Sedoheptose
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