The electron, its isolation and measurement and the determination of some of its propertiesMillikan, Robert Andrews
Philosophy
The electron, its isolation and measurement and the determination of some of its properties
Millikan, Robert Andrews
Electrons
Now, the kinetic energy of agitation of a molecule as deduced from the
value of herewith obtained, and the kinetic theory equation,
, is .
According to the Maxwell-Boltzmann Law of the partition of energy,
which certainly holds in gases, this should also be the kinetic energy
of agitation of an ion. It will be seen that the value of this energy
is approximately three times that required to push a single ion up to
the surface of the drop in question. Hence the electrostatic forces
due to 16 electrons on the drop are too weak to exert much influence
upon the motion of an approaching ion. But if it were possible to
[Pg 82]
load up a drop with negative electricity until the potential energy of
its charge were about three times as great as that computed above for
this drop, then the phenomenon here observed of the catching of new
negative ions by such a negatively charged drop should not take place,
save in the exceptional case in which an ion might acquire an energy of
agitation considerably larger than the mean value. Now, as a matter of
fact, it was regularly observed that the heavily charged drops had a
very much smaller tendency to pick up new negative ions than the more
lightly charged drops, and, in one instance, we watched for four hours
another negatively charged drop of radius .000658 cm., which carried
charges varying from 126 to 150 elementary units, and which therefore
had a potential energy of charge (computed as above on the assumption
of uniform distribution) varying from to . In all that time this drop picked up but one single
negative ion when the field was off, and that despite the fact that
the ionization was several times more intense than in the case of the
drop of Table I. Positive ions too were being caught at almost every
trip down under gravity. (The strong negative charge on the drop was
maintained by forcing on negative ions by the field as explained above.)
V. POSITIVE AND NEGATIVE ELECTRONS EXACTLY EQUAL
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