The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
On the basis of these views, we have in sodium chloride NaCl a
substance, whose molecules contain an atom, Na, with a tremendous
‹tendency to lose an electron›, and an atom, Cl, which has
a tremendous ‹affinity for an electron›. It is natural to
suppose, then, that ‹both tendencies will be satisfied by the
passage of an electron from the sodium to the chlorine atom›,
NaCl → Na^{-ε}Cl^{+ε}. Or, if we use the sign + to designate the
positive charge produced on an atom by the loss of an electron and
the sign − to indicate the charge gained through the assumption of
an electron, we have[71]: NaCl is Na^{+}Cl^{−}. Similarly we have
in hydrogen chloride H^{-ε}Cl^{+ε} or H^{+}Cl^{−}. It is altogether
likely, therefore, that the atoms in a molecule of sodium chloride
or of hydrogen chloride already possess electric charges,[72] so
that, even while combined, [p044] their tendencies to lose or gain
electrons are satisfied. It is also possible that the atoms are held
together in the molecule by the electrical attraction of the opposite
charges.[73] The force with which opposite electrical charges
attract each other depends, as is well known, on the nature of the
‹surrounding medium›. Now, when molecular sodium chloride or hydrogen
chloride is dissolved in water (a favorable medium), a decided
decrease in the attraction (see p. 62), between the charged atoms
within the molecules is brought about, and a process of ‹ionization›
results: H^{+}Cl^{−} ⇄ H^{+} + Cl^{−}. The charged particles are
called ‹ions› only after they have separated from one another and
have become independent molecules, capable, for example, of moving in
‹opposite› directions.
While the atoms of some metallic elements tend to lose a single
electron and form ions Me^{+} (‹e.g.› Na^{+}, K^{+}), the atoms of
other elements tend to lose two or more electrons, forming bivalent
ions, Me^{2+} (‹e.g.› Zn^{2+}, Fe^{2+}, etc.), or trivalent ions,
Me^{3+} (‹e.g.› Bi^{3+}, Fe^{3+}), and so forth. Similarly, atoms of
the so-called negative elements may assume two or more electrons,
forming bivalent ions, X^{2−} (‹e.g.› S^{2−}), and so forth.
«The Validity of the Theory of Ionization.»—In determining the
validity of the theory of ionization, we may consider, first, the
sufficiency of the explanations which it offers for observed facts
and important phenomena. We may then weigh, more critically, by any
evidence offering itself, the facts which will enable us to decide
between this theory and the older theory of ionization, that of
Clausius (p. 51). The latter, although displaced, is still often
revived by opponents of the modern theory. Such facts as we will
consider are found, first, in the domain of ‹conductivity phenomena›,
next, in the ‹osmotic pressure› and related properties of solutions,
and, finally, in the study of the ‹chemical activity› of electrolytes
(see Chapter V).
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