The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
The dissociation of hydrogen chloride may be expressed, in
the terms of the assumptions made, in the following equation:
HCl ⇄ H^{+} + Cl^{−}; that is, hydrogen chloride is dissociated, to a
greater or smaller extent and in reversible fashion, into positively
charged hydrogen ions H^{+}, and negatively charged chloride ions
Cl^{−}, and the charge on each chloride ion is equal in quantity
to the positive charge on each hydrogen ion. Zinc chloride is
dissociated according to the equation ZnCl_{2} ⇄ Zn^{2+} + 2 Cl^{−},
and, according to (2), the charge on each zinc ion is twice as great
in quantity as the charge on each chloride ion, and therefore twice
as great also as the charge on each hydrogen ion (see below, p.
58). It is practically certain, according to more recent results,
that the ions are combined with water to form hydrates, such as
H^{+}(H_{2}O)_{‹x›} and Cl^{−}(H_{2}O)_{‹y›}.[65] This does not
modify, essentially, the fundamental assumptions of the theory, but
contributes rather to a satisfactory explanation of the rôle of water
as an ionizing agent, a question to which we shall return later.
«The Theory of Ionization and the Electron Theory of Electricity
and of Matter.»[66]—According to the views held by many leading
physicists at the present time, ‹negative electricity› consists
of ultimate particles of matter called electrons or corpuscles.
The mass of an electron is about 1 / 1000 the mass of an atom of
hydrogen, and the electric charge of the electron is equal to that
carried by a chloride ion in solution.[67] The atoms of the elements
are considered to consist of aggregations of large numbers of
electrons in a kind of "shell" or "body" of positive electricity.
This positive electricity, in a given atom, is equal in quantity to
the total negative charge of the electrons in the atom, the atoms
as such [p043] containing no excess of either positive or negative
electricity. The number of electrons in the atom of an element is
considered to be definite and constant for that element, but the
number varies as we go from the atoms of one element to those of a
second element, the number increasing with the atomic weight of the
element.
One of the most fundamental and most characteristic properties of
elements is considered to be the ‹affinity which their atoms show
for electrons›; thus, the atoms of metals like sodium and potassium,
which are generally called "electropositive" elements,[68] show an
enormous tendency ‹to lose one electron› each and to form positively
charged particles[69] Na^{-ε} (= Na^{+}) and K^{-ε} (= K^{+}).[70]
The atoms of strongly electronegative elements, like chlorine, have
a tremendous tendency for ‹gaining› and ‹holding electrons› beyond
the number originally in such atoms. Thus, chlorine atoms tend to
‹assume an electron› each; they thereby become ‹negatively charged›
particles, Cl^{+ε} ( = Cl^{−}).
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account