The Gases of the Atmosphere: The History of Their Discovery — John Shaqi
The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
This air is not a “dry acid of nitre converted into elastic vapours,”
for it does not produce nitre with alkalies; moreover, it can be
prepared from substances which have nothing in common with nitre, no
compound of nitre having been used during their preparation. Scheele
next describes experiments proving that “fire-air” is produced by the
distillation of black oxide of manganese with concentrated oil of
vitriol, or with the “phosphorus acid of urine” (phosphoric acid), by
distilling nitrate of magnesium, made by dissolving the “white magnesia
employed in medicine” (magnesium carbonate) in _aquafortis_ (nitric
acid), or by distilling “mercurial nitre” (mercuric nitrate). The
cheapest and the best method of producing “fire-air” is to distil
purified nitre in a glass retort. But Scheele also obtained it from
“calx of silver” (silver carbonate) prepared from silver nitrate and
“alkali of tartar” (potassium carbonate); during this process he got
aerial acid, which had been present originally in the alkali of tartar;
but it was easily removed by means of milk of lime. Similarly, “calx of
gold,” obtained from a solution of gold with “alkali of tartar,” gave
“fire-air” when heated; but no aerial acid, for that air escapes during
the precipitation of the “calx.” The brown-red precipitate obtained by
adding “alkali of tartar” to “corrosive sublimate” (potassium carbonate
to mercuric chloride, giving a basic carbonate of mercury and potassium
chloride) yielded a mixture of fire-air and aerial acid when heated.
But if the “calx of mercury” had been prepared by means of the “acid
of nitre,” or in modern language by heating mercuric nitrate, a pure
“fire-air,” unmixed with “aerial acid,” was the product. And lastly,
arsenic acid, when heated, gave ordinary white arsenic together with
“fire-air.”
This fire-air was completely absorbed by “liver of sulphur” (a
polysulphide of potassium, formed by heating together potassium
carbonate and sulphur); and a mixture of four parts of “fire-air” with
fourteen parts of “vitiated air” lost the whole of its fire-air on
standing for fourteen days in contact with liver of sulphur. Dippel’s
animal oil, and burning phosphorus, charcoal, and sulphur, all absorbed
“fire-air”--completely if it was pure, incompletely if it was mixed
with “vitiated air”; in short, the identity of “fire-air” prepared from
calces, etc., with that in ordinary air was completely established.
As “vitiated air” is lighter than ordinary air, it follows that
“fire-air” must be heavier; and experiment proved this to be the case.
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