The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
“I have already stated that I was not able to find again the lost air.
One might indeed object that the lost air remains in the residual
air which can no more unite with phlogiston; for, since I have found
that it is lighter than ordinary air, it might be believed that the
phlogiston, united with this air, makes it lighter, as appears to
be known already from other experiments. But since phlogiston is a
substance, which always presupposes some weight, I much doubt whether
such hypothesis has any foundation.”[17] He had formerly conjectured
that hydrogen, the “air” obtained by the action of vitriol on zinc,
might be phlogiston; “still, other experiments are contrary to this.”
Scheele next directs attention to acid of nitre, and points out that
when prepared in absence of organic material, it is nearly colourless;
but that if phlogiston be given to it, it becomes red. At the end of a
distillation of pure nitre with pure sulphuric acid, however, red fumes
are produced: “Where does the acid now obtain its phlogiston? There is
the difficulty.”
He collected some of this “red air” in a bladder containing milk of
lime, to prevent its corrosive action; and having tried whether the
resulting gas, which was now no longer red, would support combustion,
“the candle began to burn with a large flame, whereby it gave out such
a bright light that it was sufficient to dazzle the eyes. I mixed one
part of this air with three parts of that air in which fire would
not burn; I had here an air which was like the ordinary air in every
respect. Since this air is necessarily required for the origination of
fire, and makes up about the third part of our common air, I shall call
it after this, for the sake of shortness, Fire-air; but the other air,
which is not in the least serviceable for the fiery phenomena, I shall
designate after this with the name already known, Vitiated air.”[18] How
history repeats itself! Here is Scheele, in 1772, reproducing Mayow’s
name “fire-air particles” for the same substance of which Mayow had
inferred the existence a century before, and which he had pointed out
as being present in the acid of nitre, as well as in common air.
Public-domain text, read in full here on John Shaqi.
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