The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
By this time his theory was well developed. He accounted for the
phenomena of combustion without having recourse to the phlogistic
hypothesis: the calx was produced by the union of the metal with the
active constituent of air; and when carbonaceous material burned,
the carbon united with this same constituent, producing fixed air.
But there were still difficulties in his way: it was known that in
dissolving metals in dilute vitriol or muriatic acid, a combustible and
very light air was evolved; and that the metals were thereby converted
into calces in combination with the respective acids. This fact was not
explained even by the supporters of the phlogistic theory, but it had
the effect of preventing them from accepting Lavoisier’s views. Some
considered that hydrogen and phlogiston were identical, and that on
dissolving a metal the calx was formed by the escape of the phlogiston;
while others had a hazy idea that hydrogen was a compound of water and
phlogiston; but of this more hereafter.
Lavoisier’s objection to such a theory was that the calx was _heavier
than the metal_, and that hydrogen, though light, still possessed
weight.[22] Moreover, he had ascertained that the calces of mercury,
tin, and lead are compounds of these metals with active air, and that
as fixed air is produced by heating such calces with carbon, fixed
air must be a compound of carbon and vital air, or, as he named it,
the “oxygine principle,” inasmuch as its combination with phosphorus,
sulphur, and carbon resulted in the formation of acids (=ὀξύς=,
an acid).
In 1777 he read another memoir, “On the Solution of Mercury in
Vitriolic Acid, and on the Resolution of that Acid into Aeriform
Sulphurous Acid, and into Air eminently respirable.” Priestley had
already shown that this process yielded sulphur dioxide; Lavoisier
carried the temperature higher, and, decomposing the sulphate of
mercury, produced metallic mercury, sulphur dioxide, and oxygen. It
appeared therefore that sulphurous differed from sulphuric acid in
containing a smaller proportion of oxygen.
He also experimented with iron pyrites, and his experiments recall
those of Boyle. Boyle found that “marcasite,” a disulphide of iron, on
exposure to air, gained in weight, while vitriol of iron was formed.
Lavoisier performed the same experiment, not “in a very pure air,” as
Boyle did when he left the pyrites exposed in a quiet dust-free room,
but in a confined quantity of ordinary air; and he found that the air
was rendered incapable of supporting combustion, or, in other words,
its oxygen was removed.
Public-domain text, read in full here on John Shaqi.
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