The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
The English degree is a survival of the time when the atomic weight of
sodium was believed to be twenty-four instead of twenty-three, and,
since the error on 76 per cent. Na_{2}O due to this amounts to about 1
per cent., may be obtained by adding this figure to the sodium oxide
really present.
_Caustic soda_ (sodium hydrate) comes into commerce in a liquid form as
90 deg. Tw. (and even as high as 106 deg. Tw.), and other degrees of dilution,
and also in a solid form in various grades as 60 deg., 70 deg., 76-77 deg., 77-78 deg.
These degrees represent the percentage of sodium oxide (Na_{2}O) present
plus the 1 per cent. The highest grade, containing as it does more
available caustic soda and less impurities, is much more advantageous in
use.
_Carbonate of soda_ or _soda ash_, 58 deg., also termed "light ash," and
"refined alkali". This is a commercially pure sodium carbonate
containing about 0.5 per cent. salt (NaCl). The 58 deg. represents the
English degrees and corresponds to 99 per cent. sodium carbonate
(Na_{2}CO_{3}).
_Soda ash_, 48 deg., sometimes called "caustic soda ash," often contains
besides carbonate of soda, 4 per cent. caustic soda (sodium hydrate),
and 10 per cent. salt (sodium chloride), together with water and
impurities.
The 48 degrees refers to the amount of alkali present in terms of sodium
oxide (Na_{2}O), but expressed as English degrees.
_Caustic potash_ (potassium hydrate) is offered as a liquid of 50-52 deg. B.
(98-103 deg. Tw.) strength, and also in solid form as 75-80 deg. and 88-92 deg. The
degrees in the latter case refer to the percentage of potassium hydrate
(KHO) actually present.
_Carbonate of Potash._--The standard for refined carbonate of potash is
90-92 per cent. of actual potassium carbonate (K_{2}CO_{3}) present,
although it can be obtained testing 95-98 per cent.
OTHER MATERIALS.
_Water._--Water intended for use in soap-making should be as soft as
possible. If the water supply is hard, it should be treated chemically;
the softening agents may be lime and soda ash together, soda ash alone,
or caustic soda. There are many excellent plants in vogue for water
softening, which are based on similar principles and merely vary in
mechanical arrangement. The advantages accruing from the softening of
hard water intended for steam-raising are sufficiently established and
need not be detailed here.
_Salt_ (sodium chloride or common salt, NaCl) is a very important
material to the soap-maker, and is obtainable in a very pure state.
Brine, or a saturated solution of salt, is very convenient in
soap-making, and, if the salt used is pure, will contain 26.4 per cent.
sodium chloride and have a density of 41.6 deg. Tw. (24.8 deg. B.).
The presence of sulphates alters the density, and of course the sodium
chloride content.
Salt produced during the recovery of glycerine from the spent lyes often
contains sulphates, and the density of the brine made from this salt
ranges higher than 42 deg. Tw. (25 deg. B.).
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