The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
Were we to admit the existence of an ore composed of lead and silver,
it is obvious that no such products could be obtained by simply
smelting it.
Cassiteros, or tin, is mentioned by Homer; and, from the way in which
the metal is said by him to have been used, it is obvious that in his
time it bore a much higher price, and, consequently, was more valued
than at present. In his description of the breastplate of Agamemnon, he
says that it contained ten bands of steel, twelve of gold, and twenty
of tin (κασσιτεροιο).[57] And in the twenty-third book of the Iliad
(line 561), Achilles describes a copper breastplate surrounded with
shining tin (φαεινου κασσιτεροιο). Pliny informs us, that in his time
tin was adulterated by adding to it about one-third of white copper. A
pound of tin, when Pliny lived, cost ten denarii. Now, if we reckon a
denarius at 7¾_d._, with Dr. Arbuthnot, this would make a Roman pound
of tin to cost 6_s._ 5½_d._ But, as the Roman pound was only equal to
three-fourths of our avoirdupois pound, it is plain that in the time
of Pliny an avoirdupois pound of tin was worth 8_s._ 7¼_d._, which is
almost seven times the price of tin in the present day.
[57] Iliad xi. 25.
Tin, in the time of Pliny, was used for covering the inside of copper
vessels, as it is at this day. And, no doubt, the process still
followed is of the same nature as the process used by the ancients for
tinning copper. Pliny remarks, with surprise, that copper thus tinned
does not increase in weight. Now Bayen ascertained that a copper pan,
nine inches in diameter, and three inches three lines in depth, when
tinned, only acquired an additional weight of twenty-one grains. These
measures and weights are French. When we convert them into English, we
have a copper pan 9·59 inches in diameter, and 3·46 inches deep, which,
when tinned, increased in weight 17·23 troy grains. Now the surface
of the copper pan, thus tinned, was 176·468 square inches. Hence it
follows, that a square inch of copper, when tinned, increases in weight
only 0·097 grains. This increase is so small, that we may excuse Pliny,
who probably had never seen the increase of weight determined, except
by means of a rude Roman statera, for concluding that there was no
increase of weight whatever.
Tin was employed by the ancients for mirrors: but mirrors of silver
were gradually substituted; and these in Pliny’s time had become so
common, that they were even employed by female servants or slaves.
That Pliny’s knowledge of the properties of tin was very limited, and
far from accurate, is obvious from his assertion that _tin_ is less
fusible than silver.[58] It is true that the ancients had no measure
to determine the different degrees of heat; but as tin melts at a heat
under redness, while silver requires a bright red heat to bring it into
fusion, a single comparative trial would have shown him which was most
fusible. This trial, it is obvious, had never been made by him.
[58] Lib. xxxiv. c. 17.
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