The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
2. _Yellow paints._ All the _yellows_ examined by Davy proved to be
_iron ochres_, sometimes mixed with a little _red lead_. Orpiment
was undoubtedly employed, as is obvious from what Pliny says on the
subject: but Davy found no traces of it among the yellow colours which
he examined. A very deep yellow, approaching orange, which covered a
piece of stucco in the ruins near the monument of Caius Cestius, proved
to be protoxide of lead, or massicot, mixed with some red lead. The
yellows in the Aldobrandini pictures were all ochres, and so were those
in the pictures on the walls of the houses at Pompeii.
3. _Blue paints._ Different shades of blues are used in the different
apartments of the baths of Titus, which are darker or lighter, as they
contain more or less carbonate of lime with which the blue pigment
had been mixed by the painter. This blue pigment turned out, on
examination, to be a frit composed of alkali and silica, fused together
with a certain quantity of oxide of copper. This was the colour
called χυανος (_kyanos_) by the Greeks, and _cæruleum_ by the Romans.
Vitruvius gives the method of preparing it by heating strongly together
sand, carbonate of soda, and filings of copper. Davy found that
fifteen parts by weight of anhydrous carbonate of soda, twenty parts
of powdered opaque flints, and three parts of copper filings, strongly
heated together for two hours, gave a substance exactly similar to
the blue pigment of the ancients, and which, when powdered, produced
a fine deep blue colour. This cæruleum has the advantage of remaining
unaltered even when the painting is exposed to the actions of the air
and sun.
There is reason to suspect, from what Vitruvius and Pliny say, that
glass rendered blue by means of cobalt constituted the basis of some
of the blue pigments of the ancients; but all those examined by Davy
consisted of glass tinged blue by copper, without any trace of cobalt
whatever.
4. _Green paints._ All the green paints examined by Davy proved to be
carbonates of copper, more or less mixed with carbonate of lime. I have
already mentioned that verdigris was known to the ancients. It was no
doubt employed by them as a pigment, though it is not probable that the
acetic acid would be able to withstand the action of the atmosphere for
a couple of thousand years.
5. _Purple paints._ Davy ascertained that the colouring matter of
the ancient purple was combustible. It did not give out the smell of
ammonia, at least perceptibly. There is little doubt that it was the
_purpurissum_ of the ancients, or a clay coloured by means of the
purple of the buccinum employed by the Syrians in the celebrated purple
dye.
6. _Black and brown paints._ The black paints were lamp-black: the
browns were some of them ochres and some of them oxides of manganese.
Public-domain text, read in full here on John Shaqi.
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