The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
He relates, that for two moderate-sized
colourless drinking-glasses the Emperor Nero paid 6000 sistertii, which
is equivalent to 25_l._ of our money.
[73] Job xxviii. 17.
[74] Plinii Hist. Nat. xxxvi. 26.
Pliny relates the story of the man who brought a vessel of malleable
glass to the Emperor Tiberius, and who, after dimpling it by dashing
it against the floor, restored it to its original shape and beauty by
means of a hammer; Tiberius, as a reward for this important discovery,
ordered the artist to be executed, in order, as he alleged, to prevent
gold and silver from becoming useless. But though Pliny relates this
story, it is evident that he does not give credit to it; nor does it
deserve credit. We can assign no reason why malleable substances may
not be transparent; but all of them hitherto known are opaque. Chloride
of silver, chloride of lead and iron constitute no exception, for
they are not malleable, though by peculiar contrivances they may be
extended; and their transparency is very imperfect.
Many specimens of the coloured glasses made by the ancients still
remain, particularly the beads employed as ornaments to the Egyptian
mummies. Of these ancient glasses several have been examined chemically
by Klaproth, Hatchett, and some other individuals, in order to
ascertain the substances employed to give colour to the glass. The
following are the facts that have been ascertained:
1. _Red glass._ This glass was opaque, and of a lively copper-red
colour. It was probably the kind of red glass to which Pliny gave the
name of hæmatinon. Klaproth analyzed it, and obtained from 100 grains
of it the following constituents:
Silica 71
Oxide of lead 10
Oxide of copper 7·5
Oxide of iron 1
Alumina 2·5
Lime 1·5
-----
93·5[75]
[75] Beitrage, vi. 140.
No doubt the deficiency was owing to the presence of an alkali. From
this analysis we see that the colouring matter of this glass was _red
oxide of copper_.
2. _Green glass._ The colour was light verdigris-green, and the glass,
like the preceding, was opaque. The constituents from 100 grains were,
Silica 65
Black oxide of copper 10
Oxide of lead 7·5
Oxide of iron 3·5
Lime 6·5
Alumina 5·5
-----
98·0[76]
[76] Ibid., p. 142.
Thus it appears that both the red and green glass are composed of the
same ingredients, though in different proportions. Both owe their
colour to copper. The red glass is coloured by the red oxide of that
metal; the green by the black oxide, which forms green-coloured
compounds, with various acids, particularly with carbonic acid and with
silica.
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