The History of Chemistry, Volume 2 (of 2) — John Shaqi
The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
1. Scheele's first paper was published by Retzius, in 1770; it gives a
method of obtaining pure tartaric acid: the process was to decompose
cream of tartar by means of chalk. One half of the tartaric acid unites
to the lime, and falls down in the state of a white insoluble powder,
being _tartrate of lime_. The cream of tartar, thus deprived of half
its acid, is converted into the neutral salt formerly distinguished
by the name of _soluble tartar_, from its great solubility in water:
it dissolves, and may be obtained in crystals, by the usual method of
crystallizing salts. The tartrate of lime is washed with water, and
then mixed with a quantity of dilute sulphuric acid, just capable of
saturating the lime contained in the tartrate of lime; the mixture
is digested for some time; the sulphuric acid displaces the tartaric
acid, and combines with the lime; and, as the sulphate of lime is but
very little soluble in water, the greatest part of it precipitates,
and the clear liquor is drawn off: it consists of tartaric acid,
held in solution by water, but not quite free from sulphate of lime.
By repeated concentrations, all the sulphate of lime falls down,
and at last the tartaric acid itself is obtained in large crystals.
This process is still followed by the manufacturers of this country;
for tartaric acid is used to a very considerable extent by the
calico-printers, in various processes; for example, it is applied,
thickened with gum, to different parts of cloth dyed Turkey red; the
cloth is then passed through water containing the requisite quantity of
chloride of lime: the tartaric acid, uniting with the lime, sets the
chlorine at liberty, which immediately destroys the red colour wherever
the tartaric acid has been applied, but leaves all the other parts of
the cloth unchanged.
2. The paper on _fluoric acid_ appeared in the Memoirs of the Stockholm
Academy, for 1771, when Scheele was in Scharenberg's apothecary's
shop in Stockholm, where, doubtless, the experiments were made. Three
years before, Margraaf had attempted an analysis of fluor spar, but
had discovered nothing. Scheele demonstrated that it is a compound of
lime and a peculiar acid, to which he gave the name of _fluoric_ acid.
This acid he obtained in solution in water; it was separated from
the fluor spar by sulphuric, muriatic, nitric, and phosphoric acids.
When the fluoric acid came in contact with water, a white crust was
formed, which proved, on examination, to be silica. Scheele at first
thought that this silica was a compound of fluoric acid and water; but
it was afterwards proved by Weigleb and by Meyer, that this notion is
inaccurate, and that the silica was corroded from the retort into which
the fluor spar and sulphuric acid were put. Bergman, who had adopted
Scheele's theory of the nature of silica, was so satisfied by these
experiments, that he gave it up, as Scheele himself did soon after.
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