The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Scheele did not obtain fluoric acid in a state of purity, put only
_fluosilicic acid_; nor were chemists acquainted with the properties
of fluoric acid till Gay-Lussac and Thenard published their Recherches
Physico-chimiques, in 1811.
3. Scheele's experiments on _manganese_ were undertaken at the request
of Bergman, and occupied him three years; they were published in the
Memoirs of the Stockholm Academy, for 1774, and constitute the most
memorable and important of all his essays, since they contain the
discovery of two new bodies, which have since acted so conspicuous a
part, both in promoting the progress of the science, and in improving
the manufactures of Europe. These two substances are _chlorine_ and
_barytes_, the first account of both of which occur in this paper.
The ore of manganese employed in these experiments was the _black
oxide_, or _deutoxide_, of manganese, as it is now called. Scheele's
method of proceeding was to try the effect of all the different
reagents on it. It dissolved in sulphurous and nitrous acids, and the
solution was colourless. Dilute sulphuric acid did not act upon it,
nor nitric acid; but concentrated sulphuric acid dissolved it by the
assistance of heat. The solution of sulphate of manganese in water was
colourless and crystallized in very oblique rhomboidal prisms, having
a bitter taste. Muriatic acid effervesced with it, when assisted by
heat, and the elastic fluid that passed off had a yellowish colour, and
the smell of aqua regia. He collected quantities of this elastic fluid
(_chlorine_) in bladders, and determined some of its most remarkable
properties: it destroyed colours, and tinged the bladder yellow,
as nitric acid does. This elastic fluid, in Scheele's opinion, was
muriatic acid deprived of phlogiston. By phlogiston Scheele meant, in
this place, hydrogen gas. He considered muriatic acid as a compound
of chlorine and hydrogen. Now this is the very theory that was
established by Davy in consequence of his own experiments and those of
Gay-Lussac and Thenard. Scheele's mode of collecting chlorine gas in a
bladder, did not enable him to determine its characters with so much
precision as was afterwards done. But his accuracy was so great, that
every thing which he stated respecting it was correct so far as it went.
Public-domain text, read in full here on John Shaqi.
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