The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
long time in a glass retort, a little silica makes its appearance; but
he showed that this silica was wholly derived from the retort. Glass,
it is well known, is a compound of silica and a fixed alkali. When
water is long digested on it the glass is slightly corroded, a little
alkali is dissolved in the water and a little silica separated in the
form of a powder.
He turned a good deal of his attention also to geology, and made
repeated journeys with Guettard into almost every part of France.
The object in view was an accurate description of the mineralogical
structure of France--an object accomplished to a considerable extent by
the indefatigable exertions of Guettard, who published different papers
on the subject in the Memoirs of the French Academy, accompanied with
geological maps; which were at that time rare.
The mathematical sciences also engrossed a considerable share of his
attention. In short he displayed no great predilection for one study
more than another, but seemed to grasp at every branch of science with
equal avidity. While in this state of suspension he became acquainted
with the new and unexpected discoveries of Black, Cavendish, and
Priestley, respecting the gases. This opened a new creation to his
view, and finally determined him to devote himself to scientific
chemistry.
In the year 1774 he published a volume under the title of "Essays
Physical and Chemical." It was divided into two parts. The first part
contained an historical detail of every thing that had been done on
the subject of airs, from the time of Paracelsus down to the year
1774. We have the opinions and experiments of Van Helmont, Boyle,
Hales, Boerhaave, Stahl, Venel, Saluces, Black, Macbride, Cavendish,
and Priestley. We have the history of Meyer's acidum pingue, and the
controversy carried on in Germany, between Jacquin on the one hand, and
Crans and Smeth on the ether.
In the second part Lavoisier relates his own experiments upon gaseous
substances. In the first four chapters he shows the truth of Dr.
Black's theory of fixed air. In the 4th and 5th chapters he proves that
when metallic calces are reduced, by heating them with charcoal, an
elastic fluid is evolved, precisely of the same nature with carbonic
acid gas. In the 6th chapter he shows that when metals are calcined
their weight increases, and that a portion of air equal to their
increase in weight is absorbed from the surrounding atmosphere. He
observed that in a given bulk of air calcination goes on to a certain
point and then stops altogether, and that air in which metals have
been calcined does not support combustion so well as it did before any
such process was performed in it. He also burned phosphorus in a given
volume of air, observed the diminution of volume of the air and the
increase of the weight of the phosphorus.
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