In 1823 Mr. Faraday made the important discovery that under certain
conditions of temperature and pressure many gases could be liquefied,
and that these liquids exerted great expansive force by slight additions
of temperature, returning quickly with regularity and certainty to their
original state upon the application of cold.
The discovery of this new force appeared of such importance, that Mr.
Faraday lost no time in publishing it to the world; and Sir Isambard
Brunel very soon afterwards commenced a series of experiments to
determine the value of the liquid gas as a mechanical agent.
The first experiments were made at Chelsea; but the prosecution of them
was soon transferred to the care of Mr. Brunel at Rotherhithe, where he
devoted all his spare time to the construction of his father’s proposed
‘Differential Power Engine.’
That the progress of this discovery, and of the experiments made with a
view to the application of the liquid gas, as a motive power, may be
understood, it is necessary to state that in March 1823 Mr. Faraday
communicated to the Royal Society the results of his first experiments
on the liquefaction of gases.
The fluid was then produced by the decomposition of the hydrate of
chlorine by heat in a closed tube, the amount of gas evolved being so
great as to produce a pressure in the tube sufficient to condense the
gas into a fluid of the same volume.
This interesting experiment was followed by others with that rapidity
and success so remarkable in everything undertaken at that time in the
laboratory of the Royal Institution; and within a month another paper
was read before the Royal Society, in which the degrees of pressure and
temperature at which several gases could be liquefied were recorded, and
the means employed to produce and liquefy each gas accurately described.
On April 17 a third paper was communicated by Mr. Faraday, ‘On the
Application of Liquids produced by the Condensation of Gases as
Mechanical Agents.’
The question is thus stated: ‘The ratio of the elastic force dependent
upon pressure is to be combined with that of the expansive force
dependent on temperature; and the development of latent heat on
compression and the necessity of its reabsorption in expansion must
awaken doubts as to the economical results to be obtained by employing
the steam of water under very great pressures and very elevated
temperatures.
No such doubt can arise respecting liquids, which require for their
existence even a compression equal to thirty or forty atmospheres, and
where slight elevations of temperature are sufficient to produce an
immense elastic force, and where the principal question arising is
whether the effort of mechanical motion is to be most easily produced by
an increase or diminution of heat by artificial means.’
Public-domain text, read in full here on John Shaqi.
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