This view of the composition of the spectrum might have long remained
unchallenged, had we not been able to apply to it a new mode of
analysis. Though we cannot separate the _green_ rays of the spectrum
into _yellow_ and _blue_ by the refraction of prisms, yet if we
possessed any substance which had a specific attraction for _blue_
rays, and which stopped them in their course, and allowed the _yellow_
rays to pass, we should thus analyze the _green_ as effectually as
if they were separated by refraction. The substance which possesses
this property is a purplish blue glass, similar to that of which
finger-glasses are made. When we view through a piece of this glass,
about the twentieth of an inch thick, a brilliant prismatic spectrum,
we find that it has exercised a most extraordinary absorptive action
on the different colours which compose it. The _red_ part of the
spectrum is divided into _two red_ spaces, separated by an interval
entirely devoid of light. Next to the inner red space comes a space
of bright _yellow_, separated from the red by a visible interval.
After the yellow comes the _green_, with an obscure space between
them, then follows the _blue_ and the _violet_, the last of which has
suffered little or no diminution. Now it is very obvious, that in this
experiment, the blue glass has actually absorbed the _red_ rays, which,
when mixed with the _yellow_ on one side, constituted _orange_, and the
_blue_ rays, which, when mixed with the _yellow_ on the other side,
constituted _green_, so that the insulation of the _yellow_ rays thus
effected, and the disappearance of the _orange_, and of the greater
part of the _green_ light, proves beyond a doubt that the _orange_
and _green_ colours in the spectrum are compound colours, the former
consisting of _red_ and _yellow_ rays, and the latter of _yellow_ and
_blue_ rays _of the very same refrangibility_. If we compare the two
red spaces of the spectrum seen through the blue glass with the red
space seen without the blue glass, it will be obvious that the red
has experienced such an alteration in its tint by the action of the
blue glass, as would be effected by the absorption of a small portion
of yellow rays; and hence we conclude, that the red of the spectrum
contains a slight tinge of yellow, and that the yellow space extends
over more than one-half of the spectrum, including the _red_, _orange_,
_yellow_, _green_, and _blue_ spaces.
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