The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The heavy metals have a specific gravity exceeding 5; they are
generally divided into groups, which are known by the name of the
commonest metal in the group. These are as follows:—
Zinc group Zinc, Zn = 65.
Iron group Iron, Fe = 56.
Tungsten group Tungsten, W = 184.
Antimony group Antimony, Sb = 120.
Tin group Tin, Sn = 119.
Lead group Lead, Pb = 207.
Silver group Silver, Ag = 108.
Gold group Gold, Au = 197.
Platinum group Platinum, Pt = 194.
To the zinc group belong the metals zinc, cadmium and indium, of which
only the two first are of importance here. The iron group comprises
iron, manganese, cobalt, nickel, chromium and uranium, all of which
are used in the manufacture of colours. The antimony group contains
antimony and bismuth, the latter of which is of little importance.
To the tin group belong tin and the rare metals titanium, zirconium,
thorium, niobium and tantalum; of these tin alone is important in
colour making. In the lead group are lead and thallium; lead produces
many important pigments. The silver group contains silver, copper and
mercury, the two latter of which are important. Of the gold group gold
alone is of interest, and its importance has been diminished by the
discovery of far cheaper substances which replace it. In the platinum
group, which contains platinum, iridium, rhodium, ruthenium, palladium
and osmium, only platinum itself is used as a colour; it is employed
in porcelain painting to produce the peculiar metallic shimmer known
technically as “lustre.”
The behaviour of the compounds, of the metals mentioned above towards
sulphuretted hydrogen is of the greatest importance to the colour
maker, since on it depends the alterability of the pigments when
exposed to the atmosphere. Many metallic compounds are unaltered by the
sulphuretted hydrogen present in the air, whilst others are in a high
degree affected by it and become gradually darker, so that their colour
may in the end approximate to black.
The pigments containing lead, copper, mercury and bismuth are extremely
susceptible to the action of sulphuretted hydrogen, by the action of
which they form black compounds. Since colours which contain these
metals are not permanent, but darken considerably, endeavours have been
made for a long time to replace them by others not susceptible to the
action of sulphuretted hydrogen. Thus it is desirable to manufacture
only colours free from metals forming black compounds with sulphuretted
hydrogen. For the same reason pigments which contain sulphur should
not be mixed with those containing metals which form black sulphur
compounds.
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