The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments — John Shaqi
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
A variety of hydrate of alumina, heavy, and therefore easily washed, is
obtained by boiling a solution of alum with a plate of zinc lying on a
copper plate until all the alumina has separated. By collecting this on
a filter and pouring hot water over it a number of times it is obtained
quite pure.
Alumina plays a particularly important part in the manufacture of
cobalt colours. When treated with a cobalt salt and heated it takes a
fine blue shade.
In the foregoing those metals and their compounds have been treated
which are extensively used in preparing colours without themselves
forming coloured compounds. The chromates and prussiates are an
exception to this. The ammonia compounds, the alkalis and alkaline
earths, also the acids, are used in making many colours, although
they do not contain colouring principles. The alumina compounds are
in similar case. Themselves colourless, they form at the same time a
carrier for the coloured compound and bring it into a suitable form for
use as a pigment.
An example will explain what we mean by “carrier” of the colouring
matter. Logwood contains a very handsome colouring matter which can be
extracted by water. In order to be able to employ this colouring matter
as a pigment it is combined with alumina, a compound insoluble in water
being formed, which is called a lake. In this compound the alumina is
to be regarded as the carrier of the colouring matter, which it has
fixed in an insoluble form.
In dyeing, which in many respects is closely allied to colour making,
the property of certain metallic compounds, themselves colourless, of
fixing dyes is commonly utilised, the metallic compound being called
the mordant. The fabric is first prepared with the metallic compound or
mordant, and the colour then formed by bringing the mordanted material
in contact with the colouring matter.
The “heavy metals” form, among their numerous compounds, a great number
of coloured substances, and several of them are distinguished by a
great wealth of coloured derivatives; for example, copper, chromium
and cobalt form coloured compounds only. Although the use of pigments
derived from the heavy metals has been considerably restricted in
recent years by the discovery of a series of colouring matters which
replace them, yet they are now, and always will be, of very great
importance in the manufacture of colours. It is, therefore, necessary
briefly to describe the various metals which are used in colour making,
so that the manufacturer may know what metals produce harmless colours,
permanent and unaltered by the atmosphere, and what do not.
The metals are divided into two great groups, designated, according
to their specific gravities, the group of the light and of the heavy
metals. The light metals comprise the alkali, alkaline earth and earth
metals, whose important compounds we have just described. The specific
gravity of each of these metals is less than five times that of water.
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