The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The cobalt compounds which are to be used in colour making must be free
from iron, nickel and arsenic, which would detract from the cleanness
of the colours. If the precipitate produced by soda contains iron it
is mixed with excess of solution of oxalic acid, and after a few hours
the cobalt oxalate is filtered from the liquid, in which all the iron
is dissolved. The cobalt oxalate can then be converted into nitrate or
chloride by treatment with nitric or hydrochloric acids.
These salts form the material for the preparation of the cobalt
compounds, a large number of which are used as extremely durable red,
blue and green pigments; several of them, such as cobalt blue, cannot
be exactly replaced by other pigments. On account of the industrial
importance of the cobalt colours, these directions for the preparation
of the soluble cobalt salts from the ores have been given with some
detail. The preparation of the cobalt colours will be given _in
extenso_ later on.
=Chromium Compounds.=—As the name indicates, this metal yields numerous
coloured compounds (χρῶμα, colour); in fact, only coloured chromium
compounds are known, and the colours are most varied—yellow, green, red
and violet. On this account the chromium compounds are among the most
important used in colour making; a great number of colours are prepared
by their aid. Chrome ironstone, as we have already stated, is the raw
material for the preparation of chromium compounds. From it potassium
bichromate is made on a large scale in special works, so that no colour
maker is compelled to prepare chromium salts himself.
When the chromium pigments contain no metal blackened by sulphuretted
hydrogen, they have the desirable property of being unaltered by the
atmosphere. Like the cobalt compounds, they are distinguished by their
great stability when heated; on this account, they have a large use in
porcelain painting.
=Molybdenum, Tungsten and Vanadium Compounds= on account of their cost
have a very limited use as pigments. Molybdenum compounds are obtained
from molybdic acid; compounds of tungsten from the metal; and those of
vanadium from ammonium vanadate.
=Antimony Compounds= can be used in the preparation of several
pigments, but, on account of their behaviour towards sulphuretted
hydrogen, the pigments cannot be regarded as really permanent, and
their use is generally diminishing. The so-called antimony vermilion is
the only antimony compound at all extensively employed.
=Bismuth Compounds= possess properties very similar to those of
antimony. Only one bismuth preparation is used as a pigment, and this
is very sensitive to the action of sulphuretted hydrogen, being changed
into black bismuth sulphide.
=Tin Compounds= are employed in two ways: some are themselves colours,
such as stannic sulphide (mosaic gold); others, themselves colourless,
are used in making pigments, as stannous and stannic chlorides.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account