The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
It is always necessary to know exactly how much lead acetate is
contained in the solutions prepared by these processes. The lead or
the litharge is therefore weighed and the volume of the lead acetate
solution measured. One hundred parts by weight of crystallised lead
acetate are obtained from 62·54 parts of lead.
Lead acetate solutions must be kept in well-covered vessels. The
carbonic acid of the air will turn the liquid turbid. The turbidity may
be removed by the addition of acetic acid.
In the following table is given the percentage of crystallised lead
acetate contained in solutions of different specific gravities:—
+--------+------------+--------+------------+
|Specific|Crystallised|Specific|Crystallised|
|Gravity.|Lead Acetate|Gravity.|Lead Acetate|
| | per cent. | | per cent. |
+--------+------------+--------+------------+
| 1·0000 | 0 | 1·1869 | 26 |
| 1·0064 | 1 | 1·1955 | 27 |
| 1·0127 | 2 | 1·2040 | 28 |
| 1·0191 | 3 | 1·2126 | 29 |
| 1·0255 | 4 | 1·2211 | 30 |
| 1·0319 | 5 | 1·2303 | 31 |
| 1·0386 | 6 | 1·2395 | 32 |
| 1·0453 | 7 | 1·2486 | 33 |
| 1·0520 | 8 | 1·2578 | 34 |
| 1·0587 | 9 | 1·2669 | 35 |
| 1·0654 | 10 | 1·2768 | 36 |
| 1·0725 | 11 | 1·2867 | 37 |
| 1·0796 | 12 | 1·2966 | 38 |
| 1·0867 | 13 | 1·3064 | 39 |
| 1·0939 | 14 | 1·3163 | 40 |
| 1·1010 | 15 | 1·3269 | 41 |
| 1·1084 | 16 | 1·3376 | 42 |
| 1·1159 | 17 | 1·3482 | 43 |
| 1·1234 | 18 | 1·3588 | 44 |
| 1·1309 | 19 | 1·3695 | 45 |
| 1·1384 | 20 | 1·3810 | 46 |
| 1·1464 | 21 | 1·3925 | 47 |
| 1·1544 | 22 | 1·4041 | 48 |
| 1·1624 | 23 | 1·4156 | 49 |
| 1·1704 | 24 | 1·4271 | 50 |
| 1·1784 | 25 | —— | —— |
+--------+------------+--------+------------+
=Basic Lead Acetate=, Pb(C₂H₃O₂)₂.2PbO.—This salt may be regarded as
a compound of neutral lead acetate with lead oxide. It is obtained
by digesting vinegar with excess of litharge or with metallic lead,
and also by treating lead acetate solution with litharge so long as
the latter is dissolved. In the method last given, 100 parts of sugar
of lead require about 118 parts of litharge to produce a saturated
solution of basic acetate. The solution of this compound is alkaline;
it turns red litmus paper blue. When exposed to the air, a turbidity
is quickly produced owing to the separation of lead carbonate. In one
white lead process basic lead acetate is the starting point of the
manufacture.
Public-domain text, read in full here on John Shaqi.
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments — John Shaqi
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