The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
_Recovery of Spent Liquor._--As it is possible to recover 75 to 80 per
cent. of the soda originally used in digesting the esparto, the washing
of the boiled grass is conducted on scientific principles in order to
ensure a maximum recovery of soda at a minimum cost.
The recovery is effected by evaporating down the black liquor, together
with the washing waters, to a thick syrupy mass, which can be burnt.
The organic and resinous constituents of the esparto which have been
dissolved out by the caustic soda, forming the soluble soda compounds,
ignite readily, and during combustion the organic soda compounds are
converted more or less completely into crude carbonate of soda.
It is obvious, then, that the cost of recovery depends mainly on the
quantity of weak washing water which has to be evaporated. Consequently
methods are devised by means of which the grass is thoroughly washed
with as little water as possible, and some of the methods are very
ingenious.
The spent liquors and washing waters are evaporated to a small bulk in
a vacuum multiple effect apparatus, and the thick liquid mass obtained
by evaporation is burnt either in a rotary furnace or on an ordinary
hearth. Every precaution is taken to effect this operation with a
minimum quantity of coal. The burning off of this mass results in the
formation of a black substance which is taken away from the furnace
and allowed to char or slowly burn until the impure white soda ash, or
carbonate of soda, is obtained.
Two systems of recovery are in general use, which deserve a brief
notice:--
_Direct Evaporation._--The liquors may be evaporated to a small bulk
ready for incineration by treatment in long shallow pans or furnaces,
the heat necessary for the process being obtained mainly from the
combustion of the thick concentrated liquor. The most familiar type of
this form of apparatus is the Porion evaporator.
[Illustration: FIG. 23.--Scott's Multiple Effect Evaporator.]
The combustion of the concentrated liquor is started by a coal furnace
at one end of the apparatus. The thick viscous mass catches fire and
burns with a fierce flame, and the heat is utilised in evaporating the
weaker liquors which flow continuously through shallow brick troughs,
the surface of which is freely exposed to the heat and flames from the
hearth where the organic soda compounds produced in the boiling of
esparto are being incinerated and converted into soda ash.
Under suitable conditions this evaporator is most economical in its
results. It can be erected cheaply, and when all the heat is fully used
in every possible direction it can be worked at a low cost compared
with the more modern multiple effect evaporators.
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