Like waves of light and sound, these waves of diffusion are refracted when
they pass from one medium into another of a different density, where they
have a different velocity. When, for instance, a diffusion wave passes from
a 5 per cent. solution of gelatine into a 10 per cent. solution, the
wave-front is retarded, the retardation being proportional to the length of
the path through the denser medium. Hence the wave-front is flattened, the
curvature of the refracted wave being less than that of the original wave
of diffusion. The contrary is the case when the wave-front passes into a
medium where its velocity is greater. The middle of the wave-front now
travels faster than the flanks, and the curvature is increased.
[Illustration: FIG. 14.--Transformation of a spherical wave-front into a
plane wave-front by a convergent diopter.]
These diffusion rings furnish us with most excellent diagrams of refraction
at a "diopter," _i.e._ a spherical surface separating two media of
different densities. Fig. 14 shows the refraction at a convergent diopter,
_i.e_. a surface where the denser medium is convex. The diffusion waves in
this case emanate from the principal focus of the diopter, and therefore
become plane on passing through the convex surface of the denser gelatine.
These periodic diffusion rings also illustrate the phenomena of colour
diffraction. Diffusion waves of different {70} wavelength are unequally
refracted by a gelatine lens. Hence rings of different wave-length which,
originating at the same spot, are at first concentric, are no longer
parallel after passing through a gelatine lens. A convergent lens which
will change the long spherical incident waves into shorter plane waves,
will transform the short incident waves into concave waves whose curvature
is opposite to that of the original waves, _i.e._ it will transform a
divergent into a convergent beam. This is an illustration of what is called
the aberration of refrangibility.
In the same way we may demonstrate the course of diffusion waves through a
gelatine prism, showing the refraction on their incidence and again on
emergence. The prism is made of a stronger gelatine solution, which is more
refractive than the gelatine around it. The waves of diffusion whilst
traversing the prism are retarded, and this retardation is greatest at the
base where the passage is longer. Hence the wave-front is tilted towards
the base of the prism, and this tilting is repeated when the wave-front
leaves the prism.
If we examine diffusion waves of different wave-length on their emergence
from the gelatine prism, we shall see that they cut one another. With a
dense prism, the wave-front of the shorter waves is more tilted towards the
base than the wave-front of the longer waves. For diffusion as for light
the shorter waves are the most refracted. Both refraction and dispersion
are due to the unequal resistances of the medium to undulatory movements of
different periodicity.
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