Pearls and mother-of-pearl both owe their iridescence to a similar ruled
structure, which is developed in the living tissue of a mollusc. They are,
in fact, periodic precipitates of phosphate and carbonate of lime deposited
in the colloidal organic substance of the mollusc. They have the same
structure and the same chemical composition; they have the same physical
properties, the glow, the fire, and the brilliancy of our spectroscopic
gratings. In these experiments, indeed, we have realized the synthesis of
the pearl, not only a chemical synthesis, but the synthesis of its
structure and organism.
We have been able to make these periodic precipitates by the reaction of a
great number of chemical substances, giving a bewildering variety of form
and structure. Some of these recall the form of various organisms, and
especially of insects, as may be seen in Fig. 18.
All the phenomena of life are periodic. The movement of heart and lungs,
sleep and waking, all nervous phenomena, have a regular periodicity. It is
possible that the study of these purely physical phenomena of periodic
precipitation may give us the key to the causation of rhythm and
periodicity in living beings.
Besides this periodic precipitation there appear to be other chemical
reactions which are periodic. Professor Bredig of Heidelberg has lately
described a curious phenomenon, the {76} periodic catalysis of peroxide of
hydrogen by mercury. He thus describes his experiment: "We place in a
perfectly clean test tube a few cubic centimetres of perfectly pure
mercury. Upon this we pour 10 c.c. of a 10 per cent. solution of hydrogen
peroxide. The mercury speedily becomes covered with a thin, brilliant
bronze-coloured pellicle which reflects light. Then little by little
catalysis of the hydrogen peroxide begins, with liberation of oxygen. After
some time, from five to twenty minutes, the liberation of gas at the
surface of the mercury ceases, the cloud formed by the gas bubbles
disappears, and the bronze mirror at the surface of the mercury lights up
with the glint of silver. There is a pause of one or more seconds, and then
the catalytic action begins afresh, commencing at the edges of the mirror.
The cloud is again formed and again disappears. This beautiful and
surprising rhythmic phenomenon may continue at regular intervals for an
hour or more."
[Illustration: FIG. 18.--Articulate form produced by periodic
precipitation.]
A slight alkalinity of the liquid is necessary to start the phenomenon.
This explains the retardation at the beginning {77} of the experiment,
since the rhythmic catalysis cannot begin until the hydrogen peroxide has
dissolved a little of the glass so as to render it slightly alkaline. The
catalytic process may, however, be set going at once by adding a trace of
potassium acetate to the solution.
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