[Illustration: FIG. 27.--Field of crystallization around a crystal of
sodium chloride in process of formation.]
If, however, a crystal or other heterogeneous structure is present, it
forms a centre of cohesion which will attach any molecules that are brought
by diffusion into its sphere of attraction. We have succeeded in
photographing the arrangement of the molecules of a liquid around a crystal
in the act of formation (Fig. 26). For this purpose we add to the solution
traces of some colloidal substance, such as gelatine or gum, so as to delay
the crystallization. It may thus be shown that the molecules of the
surrounding liquid are already arranged in crystalline order for some
distance from the crystal, forming a sort of field of crystallization. The
arrangement of this regular field varies in different cases, and is more or
less complicated according to circumstances. One of the most frequent forms
is that shown in Fig. 27, which is the field around a crystal of sodium
chloride. In the centre {86} of the crystal is a square with well-marked
outline. At each corner of this square there is a straight line at right
angles to the diagonal, which will form the sides of the crystal in process
of formation. From the middle of each side arise yet other perpendiculars,
which in their turn bear other cross lines, each new line being set at
right angles to its predecessor. A later stage of crystallization is shown
in Fig. 27, where the two squares one inside the other at an angle of 45deg
are clearly indicated.
[Illustration: FIG. 28.--Three crystals of sodium chloride in process of
formation, each in the centre of a field of crystallization.]
Every crystallizable substance gives a different characteristic field of
crystallization. In 1903, at the Congress of Angers, I terminated my
address by these words: "The field of crystallization may serve to
determine the character of a substance in solution." I have subsequently
received from Carbonell y Soles of Barcelona an interesting work on this
subject, which he contributed to the International Congress of Medicine at
Madrid in 1903, entitled _Applicacion de la crystalogenia experimental a la
investigacion toxicologica de cas alcaloides_. {87}
Six years ago I received from Australia an exceedingly beautiful photograph
of a thin pellicle found in a rain gauge. My correspondent supposed that
this strange figure might have been produced under the influence of an
electric or magnetic field. I was able to assure him by return of post that
the figure was the result of the crystallization of copper sulphate in a
colloidal medium. In return I received a letter verifying this fact, and
saying that there were copper works in the neighbourhood, and the air was
filled with the dust of copper sulphate.
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