The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
Owing to the exceptional minuteness of its particles, it is extremely
difficult to ascertain whether pure china clay or kaolin is crystalline
or amorphous. Johnson and Blake (21) found that all the specimens they
examined 'consisted largely of hexagonal plates' and that in most
kaolins 'these plates are abundant--evidently constituting the bulk of
the substance.' This observation is contrary to the experience of most
investigators, the majority of whom have found the bulk of the material
to be amorphous and sponge-like, but a small portion of it to consist of
hexagonal or rhombic crystals.
Mellor (22) has proposed the name _clayite_ for this amorphous material,
the crystalline portion being termed _kaolinite_ as suggested by Johnson
and Blake.
Both kaolinite (crystalline) and clayite (amorphous) yield
the same results on analysis and correspond very closely to
the formula H4Al2Si2O9 or Al2O3·2SiO2·2H2O, so that it is most
probable that they are the same substance in different physical states.
According to Hickling (36) the general impression that the particles of
china clay are amorphous is due to the use of microscopes of
insufficient power. With an improved instrument, Hickling claims to have
identified the 'amorphous' portion of china clay with crystalline
kaolinite, the clay particles (fig. 17) being in the form of irregular,
curved, hexagonal prisms or in isolated plates. The former show strong
transverse cleavages. The index of refraction and that of double
refraction agree with those of Anglesea kaolinite crystals, as does the
specific gravity.
In spite of their great purity, commercial china clays and kaolins are
almost devoid of plasticity, nor can this property be greatly increased
by any artificial treatment. This has led to the conclusion that
plasticity is not an essential characteristic of the clayite or
kaolinite molecules, but is due to physical causes not shown by any
investigation of the chemical composition of the material.
In addition to the specially purified kaolins just described, alkaline
kaolins, siliceous kaolins and ferruginous kaolins are obtained from
less pure rocks and do not undergo so thorough a treatment with water.
Some of these varieties are not improbably derived from transported
kaolins, as they occur in Tertiary strata, and so bear some resemblance
to the white fireclays on the Carboniferous limestone of Staffordshire,
Derbyshire and North Wales, though the latter are far more plastic.
To be of value, a china clay or kaolin must be as white as possible and
must be free from more than an insignificant percentage of metallic
oxides which will produce a colour when the clay is heated to bright
redness. If the material is to be used in the manufacture of paper,
paint or ultra-marine, these colour-producing oxides are of less
importance providing that the clay is sufficiently white in its
commercial state.
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