The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
=Commercial china clays and kaolins= in the United Kingdom are not
simple natural products but, in the state in which they are sold
commercially, have all been subjected to a careful treatment with water,
followed by a process of sedimentation whereby the bulk of the
impurities have been removed. According to the extent to which this
treatment has been carried out, they will contain 10 per cent. or more
mica and quartz, with little or no tourmaline, felspar and undecomposed
granite. In some parts of Europe and America, kaolins are found in a
state of sufficient purity to need no treatment of this kind unless they
are to be used for the very highest class of wares.
[Illustration: _Magnified 220 Diameters_
_Magnified 920 Diameters_
_Magnified 220 Diameters_
_Magnified 220 Diameters_
Crystals of Kaolinite
_Magnified 920 Diameters_
Crystals of Secondary Muscovite.
Fig. 17. Kaolinite and Mica. (_After G. Hickling_ (36).)]
Mica is usually the chief impurity as its particles are so small and
their density resembles that of the purified china clay more closely
than do the other minerals. In commerce the term _china clay_ is almost
invariably used to denote the washed material obtained from the 'china
clay rock,' but at the pits the word 'clay' is used indiscriminately for
the carclazite (p. 78) and for the material obtained from it. As the
term 'kaolin' is used indifferently abroad for the crude 'deposit' and
for the purified commercial article, it should be understood that the
following information relates solely to the substance as usually sold
and not to the crude material.
Commercial china clay or kaolin is a soft white or faintly yellowish
substance, easily reduced to an extremely fine powder, which when mixed
with twice its weight of water will pass completely through a No. 200
sieve. Its specific gravity is 2·65, but the minuteness and nature of
its smallest particles and their character are such that it will remain
in suspension in water for several days; it thus appears to possess
colloidal properties, at any rate so far as the smaller particles are
concerned. It is almost infusible, but shows signs of softening at 1880°
C. (Seger Cone 39) or at a somewhat lower temperature, according to the
proportion of impurities present. When heated with silica or with
various metallic oxides it fuses more readily owing to the formation of
silicates.
China clays and kaolins are not appreciably affected by dilute acids,
but some specimens are partially decomposed by boiling concentrated
hydrochloric acid (26) and all are decomposed by boiling sulphuric
acid, the alumina being dissolved and the silica liberated in a form
easily soluble in solutions of caustic soda or potash. This has led to
the conclusion that some kaolins may have been produced by weathering,
as the bulk of true kaolinitic clays (such as Cornish china clay) is not
affected by boiling hydrochloric acid (p. 81).
Public-domain text, read in full here on John Shaqi.
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