M. Natanson, and subsequently P. Curie and M. Meslin, have shown by
various considerations that the same result may be arrived at by
choosing units which correspond to any corresponding states; it has
also been shown that the theorem of corresponding states in no way
implies the exactitude of Van der Waals' formula. In reality, this is
simply due to the fact that the characteristic equation only contains
three constants.
The philosophical importance and the practical interest of the
discovery nevertheless remain considerable. As was to be expected,
numbers of experimenters have sought whether these consequences are
duly verified in reality. M. Amagat, particularly, has made use for
this purpose of a most original and simple method. He remarks that, in
all its generality, the law may be translated thus: If the isothermal
diagrams of two substances be drawn to the same scale, taking as unit
of volume and of pressure the values of the critical constants, the
two diagrams should coincide; that is to say, their superposition
should present the aspect of one diagram appertaining to a single
substance. Further, if we possess the diagrams of two bodies drawn to
any scales and referable to any units whatever, as the changes of
units mean changes in the scale of the axes, we ought to make one of
the diagrams similar to the other by lengthening or shortening it in
the direction of one of the axes. M. Amagat then photographs two
isothermal diagrams, leaving one fixed, but arranging the other so
that it may be free to turn round each axis of the co-ordinates; and
by projecting, by means of a magic lantern, the second on the first,
he arrives in certain cases at an almost complete coincidence.
This mechanical means of proof thus dispenses with laborious
calculations, but its sensibility is unequally distributed over the
different regions of the diagram. M. Raveau has pointed out an equally
simple way of verifying the law, by remarking that if the logarithms
of the pressure and volume are taken as co-ordinates, the co-ordinates
of two corresponding points differ by two constant quantities, and the
corresponding curves are identical.
From these comparisons, and from other important researches, among
which should be particularly mentioned those of Mr S. Young and M.
Mathias, it results that the laws of corresponding states have not,
unfortunately, the degree of generality which we at first attributed
to them, but that they are satisfactory when applied to certain groups
of bodies.[7]
[Footnote 7: Mr Preston thus puts it: "The law [of corresponding
states] seems to be not quite, but very nearly true for these
substances [_i.e._ the halogen derivatives of benzene]; but in the
case of the other substances examined, the majority of these
generalizations were either only roughly true or altogether departed
from" (_Theory of Heat_, London, 1904, p. 514.)--ED.]
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