The special object of M. Claude was to obtain oxygen in a practical
manner by the actual distillation of liquid air. Since nitrogen boils
at -194° and oxygen at -180.5° C., if liquid air be evaporated, the
nitrogen escapes, especially at the commencement of the evaporation,
while the oxygen concentrates in the residual liquid, which finally
consists of pure oxygen, while at the same time the temperature rises
to the boiling-point (-180.5° C.) of oxygen. But liquid air is costly,
and if one were content to evaporate it for the purpose of collecting
a part of the oxygen in the residuum, the process would have a very
poor result from the commercial point of view. As early as 1892, Mr
Parkinson thought of improving the output by recovering the cold
produced by liquid air during its evaporation; but an incorrect idea,
which seems to have resulted from certain experiments of Dewar--the
idea that the phenomenon of the liquefaction of air would not be,
owing to certain peculiarities, the exact converse of that of
vaporization--led to the employment of very imperfect apparatus. M.
Claude, however, by making use of a method which he calls the
reversal[8] method, obtains a complete rectification in a remarkably
simple manner and under extremely advantageous economic conditions.
Apparatus, of surprisingly reduced dimensions but of great efficiency,
is now in daily work, which easily enables more than a thousand cubic
metres of oxygen to be obtained at the rate, per horse-power, of more
than a cubic metre per hour.
[Footnote 8: Methode avec retour en arriere.--ED]
It is in England, thanks to the skill of Sir James Dewar and his
pupils--thanks also, it must be said, to the generosity of the Royal
Institution, which has devoted considerable sums to these costly
experiments--that the most numerous and systematic researches have
been effected on the production of intense cold. I shall here note
only the more important results, especially those relating to the
properties of bodies at low temperatures.
Public-domain text, read in full here on John Shaqi.
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