It is probable, moreover, that the higher regions of the atmosphere
are not composed of the same air as that around us. Sir James Dewar
points out that Dalton's law demands that every gas composing the
atmosphere should have, at all heights and temperatures, the same
pressure as if it were alone, the pressure decreasing the less
quickly, all things being equal, as its density becomes less. It
results from this that the temperature becoming gradually lower as we
rise in the atmosphere, at a certain altitude there can no longer
remain any traces of oxygen or nitrogen, which no doubt liquefy, and
the atmosphere must be almost exclusively composed of the most
volatile gases, including hydrogen, which M.A. Gautier has, like Lord
Rayleigh and Sir William Ramsay, proved to exist in the air. The
spectrum of the _Aurora borealis_, in which are found the lines of
those parts of the atmosphere which cannot be liquefied in liquid
hydrogen, together with the lines of argon, crypton, and xenon, is
quite in conformity with this point of view. It is, however, singular
that it should be the spectrum of crypton, that is to say, of the
heaviest gas of the group, which appears most clearly in the upper
regions of the atmosphere.
Among the gases most difficult to liquefy, hydrogen has been the
object of particular research and of really quantitative experiments.
Its properties in a liquid state are now very clearly known. Its
boiling-point, measured with a helium thermometer which has been
compared with thermometers of oxygen and hydrogen, is -252°; its
critical temperature is -241° C.; its critical pressure, 15
atmospheres. It is four times lighter than water, it does not present
any absorption spectrum, and its specific heat is the greatest known.
It is not a conductor of electricity. Solidified at 15° absolute, it
is far from reminding one by its aspect of a metal; it rather
resembles a piece of perfectly pure ice, and Dr Travers attributes to
it a crystalline structure. The last gas which has resisted
liquefaction, helium, has recently been obtained in a liquid state; it
appears to have its boiling-point in the neighbourhood of 6°
absolute.[11]
[Footnote 11: M. Poincaré is here in error. Helium has never been
liquefied.--ED.]
§ 3. SOLIDS AND LIQUIDS
The interest of the results to which the researches on the continuity
between the liquid and the gaseous states have led is so great, that
numbers of scholars have naturally been induced to inquire whether
something analogous might not be found in the case of liquids and
solids. We might think that a similar continuity ought to be there met
with, that the universal character of the properties of matter forbade
all real discontinuity between two different states, and that, in
truth, the solid was a prolongation of the liquid state.
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