Other nitrogenous residues are contained in the urine of animals,
and several other excretory products may be formed. But in all
these cases we can easily find subsidiary energy-transformations
effected by bacteria, as in the above scheme. This, then, is the
positive, or direct half, of that reversible Carnot cycle with
which we are comparing life. In it energy falls in potential (or
intensity, or level), and in this fall of potential transformations
are produced--exhibit themselves, is perhaps a better way of putting
it. We will consider these transformations later; in the meantime it
should be noted that in this fall of potential is a degradation of
chemical energy. Compounds, carbon dioxide, water, and nitrate are
produced which are chemically inert. It is no use to say that carbon
dioxide may react with (say) glowing magnesium, water with metallic
sodium, and nitrate with (say) glowing carbon. A condition of chemical
equilibrium would result from purely inorganic becoming on our earth in
which there was no metallic sodium or magnesium or incandescent carbon;
in which the metals would become inert oxides, and the carbon would
become dioxide. The formation of these compounds represents a limit to
energy-transformations. Note also that all these energy-transformations
are conservative; the total quantity remains unchanged throughout,
and is the same at the end as at the beginning. But _entropy has been
augmented: unavailable energy has increased at the expense of available
energy_.
Consider now the indirect, or reversed, Carnot cycle. We begin with
the inert matter, resulting from the metabolism of the animal, carbon
dioxide, water, nitrate, and a few more mineral substances. We have the
energy of solar radiation. By virtue of the living chlorophyll plastid
in the cells of the green plant, this solar radiation uses the carbon
dioxide and water as raw materials in the elaboration of starch. At the
same time it absorbs nitrate, with some other inert mineral substances
from the soil, and takes these into its tissues. The starch formed
in the chlorophyll is converted into soluble sugar, which circulates
through the vessels of the plant and is associated with the nitrogenous
salt in the elaboration of proteid. Proteid, oils, fats and resins,
and to a greater extent carbohydrates, are thus built up by the plant
and _accumulate_, for mechanical work is not done by it, nor is heat
dissipated--or at least these processes occur to an insignificant
extent.
} Metabolism --------------> are synthesised to--
Carbon dioxide } of the { proteid
Water } green { fat
Nitrate } plant { carbohydrate
Chemical energy at --------------> Chemical energy
low potential Work done on at high potential.
the system
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