The Popular Science Monthly, September, 1900: Vol. 57, May, 1900 to October, 1900Various
Science
The Popular Science Monthly, September, 1900: Vol. 57, May, 1900 to October, 1900
Various
Science -- Periodicals; Technology -- Periodicals
Every gas, when cold, absorbs the same rays of light which it emits
when incandescent.
An immediate inference from this law is that the dark lines seen in
the spectrum of the sun are caused by the passage of the light through
gases either existing on the sun or forming the atmosphere of the
earth. A second inference is that we can determine what these gases are
by comparing the position of the dark lines with that of the bright
lines produced by different gases when they are made incandescent.
Hence arose the possibility of spectrum analysis, a method which has
been applied with such success to the study of the heavenly bodies.
So far as the general constitution of bodies is concerned, the canons
of spectrum analysis are these:
Firstly, when a spectrum is formed of distinct bright lines, the light
which forms it is emitted by a transparent mass of glowing gas.
Secondly, when a spectrum is entirely continuous the light emanates
from an incandescent solid, from a body composed of solid particles,
which may be ever so small, or from a mass of incandescent gas so large
and dense as not to be transparent through and through.
Thirdly, when the spectrum is continuous, except that it is crossed
by fine dark lines, the body emitting the light is surrounded by a
gas cooler than itself. The chemical constitution of this gas can be
determined by the position of the lines.
Fourthly, if, as is frequently the case, a spectrum is composed of an
irregular row of bright and shaded portions, the body is a compound
one, partly gaseous and partly solid.
It will be seen from the preceding statement that, in reality, a mass
of gas so large as not to be transparent cannot be distinguished from
a solid. It is therefore not strictly correct to say, as is sometimes
done, that an incandescent gas always gives a spectrum of bright lines.
It will give such a spectrum only when it is transparent through and
through.[C]
[C] As this principle is not universally understood, it may be
well to remark that it results immediately from Kirchoff’s
law of the proportionality between the radiating and
absorbing powers of all bodies for light of each separate
wave-length. When a body, even if gaseous in form, is of
such great size and density that light of no color can
pass entirely through it, then the consequent absorption
by the body of light of all colors shows that throughout
the region where the absorption occurs there must be an
emission of light of these same colors. Thus light from all
parts of the spectrum will be emitted by the entire mass.
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