The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The capacity of each element to combine with one or another element,
and to form compounds with them which are in a greater or less degree
prone to give new and yet more complex substances, forms the fundamental
character of each element. Thus sulphur easily combines with the
metals, oxygen, chlorine, or carbon, whilst gold and silver enter
into combinations with difficulty, and form unstable compounds, which
are easily decomposed by heat. The cause or force which induces the
elements to enter into chemical change must be considered, as also the
cause which holds different substances in combination--that is, which
endues the substances formed with their particular degree of stability.
This cause or force is called _affinity_ (_affinitas_, _affinité_,
_Verwandtschaft_), or chemical affinity.[29] Since this force must
be regarded as exclusively an attractive force, like gravity, many
writers (for instance, Bergmann at the end of the last, and Berthollet
at the beginning of this, century) supposed affinity to be essentially
similar to the universal force of gravity, from which it only differs
in that the latter acts at observable distances whilst affinity only
evinces itself at the smallest possible distances. But chemical
affinity cannot be entirely identified with the universal attraction
of gravity, which acts at appreciable distances and is dependent
only on mass and distance, and not on the quality of the material on
which it acts, whilst it is by the quality of matter that affinity is
most forcibly influenced. Neither can it be entirely identified with
cohesion, which gives to homogeneous solid substances their crystalline
form, elasticity, hardness, ductility, and other properties, and to
liquids their surface tension, drop formation, capillarity, and other
properties, because affinity acts between the component parts of a
substance and cohesion on a substance in its homogeneity, although both
act at imperceptible distances (by contact) and have much in common.
Chemical force, which makes one substance penetrate into another,
cannot be entirely identified with even those attracting forces which
make different substances adhere to each other, or hold together (as
when two plane-polished surfaces of solid substances are brought into
close contact), or which cause liquids to soak into solids, or adhere
to their surfaces, or gases and vapours to condense on the surfaces
of solids. These forces must not be confounded with chemical forces,
which cause one substance to penetrate into the substance of another
and to form a new substance, which is never the case with cohesion.
But it is evident that the forces which determine cohesion form a
connecting-link between mechanical and chemical forces, because they
only act by intimate contact. For a long time, and especially during
the first half of this century, chemical attraction and chemical forces
were identified with electrical forces. There is certainly an intimate
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