The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
relation between them, for electricity is evolved in chemical reactions,
and has also a powerful influence on chemical processes--for instance,
compounds are decomposed by the action of an electrical current. And the
exactly similar relation which exists between chemical phenomena and the
phenomena of heat (heat being developed by chemical phenomena, and heat
being able to decompose compounds) only proves the unity of the forces
of nature, the capability of one force to produce and to be transformed
into others. For this reason the identification of chemical force
with electricity will not bear experimental proof.[30] As of all the
(molecular) phenomena of nature which act on substances at immeasurably
small distances, the phenomena of heat are at present the best
(comparatively) known, having been reduced to the simplest fundamental
principles of mechanics (of energy, equilibrium, and movement), which,
since Newton, have been subjected to strict mathematical analysis, it
is quite natural that an effort, which has been particularly pronounced
during recent years, should have been made to bring chemical phenomena
into strict correlation with the already investigated phenomena of
heat, without, however, aiming at any identification of chemical with
heat phenomena. The true nature of chemical force is still a secret
to us, just as is the nature of the universal force of gravity, and
yet without knowing what gravity really is, by applying mechanical
conceptions, astronomical phenomena have been subjected not only to
exact generalisation but to the detailed prediction of a number of
particular facts; and so, also, although the true nature of chemical
affinity may be unknown, there is reason to hope for considerable
progress in chemical science by applying the laws of mechanics to
chemical phenomena by means of the mechanical theory of heat. As yet
this portion of chemistry has been but little worked at, and therefore,
while forming a current problem of the science, it is treated more
fully in that particular field which is termed either 'theoretical'
or 'physical' chemistry, or, more correctly, _chemical mechanics_. As
this province of chemistry requires a knowledge not only of the various
homogeneous substances which have yet been obtained and of the chemical
transformations which they undergo, but also of the phenomena (of heat
and other kinds) by which these transformations are accompanied, it
is only possible to enter on the study of chemical mechanics after an
acquaintance with the fundamental chemical conceptions and substances
which form the subject of this book.[31]
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