The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[17] The periodic relations enumerated above appertain to the real
elements, and not to the elements in the free state as we know
them; and it is very important to note this, because the periodic
law refers to the real elements, inasmuch as the atomic weight is
proper to the real element, and not to the 'free' element, to
which, as to a compound, a molecular weight is proper. Physical
properties are chiefly determined by the properties of molecules,
and only indirectly depend on the properties of the atoms forming
the molecules. For this reason the periods, which are clearly and
quite distinctly expressed--for instance, in the forms of
combination--become to some extent involved (complicated) in the
physical properties of their members. Thus, for instance, besides
the _maxima_ and _minima_ corresponding with the periods and
groups, new molecules appear; thus, as regards the melting-point
of germanium, a local maximum appears, which was, however,
foreseen by the periodic law when the properties of germanium
(ekasilicon) were forecast.
As, from the necessity of the case, the physical properties must be in
dependence on the composition of a substance, _i.e._ on the quality and
quantity of the elements forming it, so for them also a dependence on the
atomic weight of the component elements must be expected, and
consequently also on their periodic distribution. We shall meet with
repeated proofs of this in the further exposition of our treatise, and
for the present will content ourselves with citing the discovery by
Carnelley in 1879 of the dependence of the magnetic properties of the
elements on the position occupied by them in the periodic system.
Carnelley showed that all the elements of the _even series_ (beginning
with lithium, potassium, rubidium, cæsium) belong to the number of
magnetic (paramagnetic) substances; for example, according to Faraday and
others,[17 bis] C, N, O, K, Ti, Cr, Mn, Fe, Co, Ni, Ce, are magnetic; and
the elements of the _uneven series are diamagnetic_, H, Na, Si, P, S, Cl,
Cu, Zn, As, Se, Br, Ag, Cd, Sn, Sb, I, Au, Hg, Tl, Pb, Bi.
[17 bis] The relation of certain elements (for instance, the analogues
of Pt) among diamagnetic and paramagnetic bodies is sometimes
doubtful (probably partly owing to the imperfect purity of the
reagents under investigation). This subject has been studied in
some detail by Bachmetieff in 1889.
Carnelley also showed that the _melting-point_ of elements varies
periodically, as is seen by the figures in Table III. (nineteenth
column),[18] where all the most trustworthy data are collected, and
predominance is given to those having maximum and minimum values.[19]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account