The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
however, very soluble in common salt solution of about 10 per cent.,
from which it was precipitated both by the addition of much water and by
saturating the solution with salt. Reimer found that a 10 per cent. salt
solution was equally effective with lime-water in extracting coriin from
the hide, and that it was partially precipitated on the addition of
acid, and completely so on saturating the acidified solution with salt.
Other salts of the alkalies and alkaline earths acted in a similar
manner, so that Reimer was at first deceived when experimenting with
baryta-water, because, being more concentrated than lime-water, the
coriin remained dissolved in the barium salt formed on neutralising with
acid, and it was necessary to dilute before a precipitate could be
obtained. The slightly acid solution of coriin gave no precipitate
either in the cold or on boiling with potassium ferrocyanide, being thus
distinguished from albuminoids. The neutral or alkaline solution showed
no precipitate with iron or mercuric chloride, copper sulphate, or with
neutral lead acetate; but with basic lead acetate, basic iron sulphate,
or an excess of tannin a precipitate was produced. Reimer’s analysis
showed: Carbon, 45·91; hydrogen, 6·57; nitrogen, 17·82; oxygen, 29·60;
and he gives a formula showing its relation to the original fibre, which
does not seem supported by sufficient evidence. In all probability
coriin is merely an impure degradation-product of hide-fibre or gelatin.
[45] Sitz. Wiener Akad., xxxix. p. 305.
[46] Ding. Polyt. Journ., ccv. p. 153.
_Hide Albumin._--The fresh hide contains a portion of actual albumin,
viz. that of the blood-serum and of the lymph, which is not only
contained in the abundant blood-vessels, but saturates the fibrous
connective tissue, of which it forms the nourishment. This albumin is
mostly removed from the skin by the liming and working on the beam,
which is preparatory to tanning. Probably for sole-leather, the albumin
itself would be rather advantageous if left in the hide, as it combines
with tannin, and would assist in giving firmness and weight to the
leather. It is, however, for reasons which will be seen hereafter,
absolutely necessary to get rid of any lime which may be in combination
with it. The blood must also be thoroughly cleansed from the hide before
tanning, as its colouring matter contains iron, which, by combination
with the tannin, produces a bad colour.
The albumins form a class of closely allied bodies of which white of egg
may be taken as a type. They are also related to the casein of milk, to
fibrin, and more distantly to gelatin. A good deal of information on the
class may be found in Watt’s Dict. of Chem., 2nd ed., article
‘Proteids,’ and Beilstein’s article ‘Albuminaten,’ and in Allen’s
‘Commercial Organic Analysis,’ vol. iv.
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