The Quarterly Journal of Science, Literature and the Arts, July-December, 1827Various
Science
The Quarterly Journal of Science, Literature and the Arts, July-December, 1827
Various
Arts -- Periodicals; Science -- Periodicals; Technology -- Periodicals
We are willing to admit that the subject of electricity is a very
difficult one for the chemist to deal with—he must necessarily say
much upon it, and is equally obliged to omit abstract details which
are often necessary to its explanation, and yet too prolix and bulky
for an elementary chemical work. So that it requires considerable
acquaintance with the subject to give a perspicuous and yet concise
abstract, [p063] such as may be useful to the student. Dr. Turner
has not been very successful in effecting this _desideratum_, and
has unnecessarily introduced two sections, the one on electricity,
the other on galvanism. He also talks of the “science of galvanism,”
which is in bad taste, and erroneously asserts that the energy of the
pile is proportional to the degree of chemical action which takes
place; a statement by no means correct, inasmuch as the energy of De
Luc’s column is directly proportional to the number of alternations,
and appears entirely independent of chemical action; and again, a
series of 2000 plates, arranged in the usual Voltaic apparatus, when
perfectly bright and clean, and the cells filled with distilled water
only, give a much more powerful shock, and cause a greater divergence
of the leaves of the electrometer than when the apparatus is charged
with diluted acids. Here, those very singular phenomena, which
electricians distinguish by the terms _quantity_ and _intensity_,
appear perfectly distinct; and between these our author does not
sufficiently discriminate, but jumbles the whole under the term
_activity_. In describing the chemical energies, too, of the pile, or
its decomposing powers, the Doctor entirely overlooks the important
and curious influence of water. He says that acids and salts are all
decomposed, without exception, one of their elements appearing at one
side of the battery, and the other at its opposite extremity; (_i.
e._ we presume, at its positive and negative poles.) But the fact is,
that, excepting where it merely acts as a source of heat, nothing
is decomposable by electricity without the intervention of water;
the hydrogen and oxygen of which respectively accompany the elements
of the other compounds. Not an atom of potassium can be obtained
unless the potassa be moistened; nor can any salt be decomposed
except water be present. Sir Humphry says, it is required, to render
the substance a conductor; but its operation is more recondite, and
there is something mysterious and still unexplained in the uniform
appearance of hydrogen and oxygen at the opposite poles, when far
apart in water, and in all other cases of true polar electro-chemical
decomposition. At page 86, the unfortunate protectors of ships’
bottoms are introduced—a subject about which the less is said the
better;—and, as to electro-magnetism, it is merely mentioned as to
its leading phenomena, in the space of three or four pages; nor
is anything new suggested upon the “Theory of the Pile,” as it is
Public-domain text, read in full here on John Shaqi.
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