The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
It is infusible, but at a red heat it loses much water, and becomes very
brittle, with increase of specific gravity; no glowing is observed. It
is attacked by boiling concentrated sulphuric acid, and by fused
potassium bisulphate; also by hydrofluoric acid (40 per cent.), with
separation of the insoluble rare earth fluorides.
No good crystals have been found, and no crystallographic data are
known; examined by polarised light it appears isotropic, but this may
be due to alteration. Colour, yellowish- to greenish-brown. Streak,
yellowish-white. Hardness 5¹⁄₂; sp. gr. 4·179, increasing to 4·678
after ignition (cf. p. 38).
The mineral was found in a granite-pegmatite at Risör, South Norway.
~Wiikite.~[75]--A mineral of very complex composition, for which no
definite formula can be assigned. Its chemical nature may be understood
from the following analytical data:
Columbic and tantalic anhydrides = 16·0; Dioxides of titanium and
zirconium = 23·4; Silica = 17·0; Ceria = 2·5; Yttria = 7·6; Scandia =
1·2; Thoria = 5·5; Ferrous oxide = 15·5; Uranic oxide = 3·6; water (and
gas) = 5·8 per cent.
[75] Crookes, _Phil. Trans._ 1908, A, ~209~, 15.
Traces of lime, magnesia, stannic oxide and sulphur are also present.
The mineral is infusible; on heating, helium, sulphuretted hydrogen and
water vapour are given off, and a white sublimate is formed. The
evolution of gas is almost explosive, the mineral breaking with a
curious fracture.
It is black and perfectly amorphous, showing no trace of crystalline
structure or action on polarised light. Hardness, 6; sp. gr. 4·85.
Wiikite is partially attacked by acids, readily by fused potassium
bisulphate. It is radioactive.
The mineral was found with monazite in a felspar quarry at Impilaks,
Lake Ladoga, Finland. It is important as the source of scandium used by
Sir William Crookes in his investigations of that element; some
specimens of the mineral contain over 1 per cent. of the oxide (see p.
44).
* * * * *
The following related minerals, of which descriptions are given in the
alphabetical list, are to be included here:
_Arrhenite_, _Chalcolamprite_, _Endeiolite_ and _Wöhlerite_, are complex
tantalo-columbates containing silica.
_Hainite_ contains both silicon and titanium.
_Dysanalyte_ is a titano-columbate believed by Hauser[76] to be merely
an impure form of perovskite (see p. 14).
[76] Vide _Zeitsch. anorg. Chem._ 1908, ~60~, 237.
_Ilmenorutile_ and _Strüverite_ are closely allied minerals believed by
Prior[77] and Schaller[78] to be isomorphous mixtures of rutile with
Tapiolite or Mossite (ferrous tantalo-columbates).
[77] _Min. Mag._ 1908, ~15~, 78.
[78] _Abstr. Chem. Soc._ 1912, ~102~, ii. 773.
_Pyrochlore_ is a complex titano-columbate containing elements of the
cerium or yttrium groups.
_Blomstrandite_ is an hydrated titano-columbate of rare earth elements,
with calcium and uranium; it must not be confused with blomstrandine.
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